Andreas Schnepf

Publications

• Reactivity of [Ge9{Si(SiMe3)3}3]- Towards Transition Metal M2+ Cations : Coordination and Redox Chemistry
  Chemistry (Weinheim an Der Bergstrasse, Germany). Oct, 2016  |   Pubmed ID: 27796057
• IPr3 Si3 Cl5 (+) : A Highly Reactive Cation with Silanide Character
  Chemistry (Weinheim an Der Bergstrasse, Germany). Jul, 2016  |   Pubmed ID: 27258331
• The Largest Metalloid Group 14 Cluster, Ge18[Si(SiMe3)3]6 : An Intermediate on the Way to Elemental Germanium
  Angewandte Chemie (International Ed. in English). Feb, 2016  |   Pubmed ID: 26822765
• {Ge9[Si(SiMe3)2(SiPh3)]3}(-): Ligand Modification in Metalloid Germanium Cluster Chemistry
  Inorganic Chemistry. Jul, 2015  |   Pubmed ID: 26154728
• Reactions with a Metalloid Tin Cluster {Sn10[Si(SiMe3)3]4}(2-): Ligand Elimination Versus Coordination Chemistry
  Chemistry (Weinheim an Der Bergstrasse, Germany). Jun, 2015  |   Pubmed ID: 26095993
• Reactions with a Metalloid Tin Cluster {Sn10[Si(SiMe3)3]4}(2-): Ligand Elimination Versus Coordination Chemistry
  Chemistry (Weinheim an Der Bergstrasse, Germany). May, 2015  |   Pubmed ID: 25892180
• {Sn10 [Si(SiMe3 )3 ]4 }(2-) : A Highly Reactive Metalloid Tin Cluster with an Open Ligand Shell
  Chemistry (Weinheim an Der Bergstrasse, Germany). Feb, 2015  |   Pubmed ID: 25430476
• Dative or Not Dative?
  Angewandte Chemie (International Ed. in English). Jun, 2014  |   Pubmed ID: 24889370
• Nanoscale Molecular Silver Cluster Compounds in Gram Quantities
  Angewandte Chemie (International Ed. in English). Mar, 2014  |   Pubmed ID: 24519816
• Dative Bonds in Main-group Compounds: a Case for Fewer Arrows!
  Angewandte Chemie (International Ed. in English). Jan, 2014  |   Pubmed ID: 24243854
• [Ge12{FeCp(CO)2}8{FeCp(CO)}2]: a Ge12 Core Resembles the Arrangement of the High-pressure Modification Germanium (II)
  Angewandte Chemie (International Ed. in English). Feb, 2013  |   Pubmed ID: 23288682
• {Sn9[Si(SiMe3)3]2}2-: a Metalloid Tin Cluster Compound with a Sn9 Core of Oxidation State Zero
  Inorganic Chemistry. Aug, 2012  |   Pubmed ID: 22804582
• {Sn9[Si(SiMe3)3]3}− and {Sn8Si[Si(SiMe3)3]3}−: Variations of the E9 Cage of Metalloid Group 14 Clusters
  Inorganic Chemistry. Apr, 2012  |   Pubmed ID: 22436071
• [Sn4Si{Si(SiMe3)3}4{SiMe3}2]: a Model Compound for the Unexpected First-order Transition from a Singlet Biradicaloid to a Classical Bonded Molecule
  Angewandte Chemie (International Ed. in English). Aug, 2011  |   Pubmed ID: 21698735
• [Si(SiMe3)3]3Ge9M(CO)3(-) (M=Cr, Mo, W): Coordination Chemistry with Metalloid Clusters
  Dalton Transactions (Cambridge, England : 2003). Jul, 2011  |   Pubmed ID: 21614350
• The Formal Combination of Three Singlet Biradicaloid Entities to a Singlet Hexaradicaloid Metalloid Ge14[Si(SiMe3)3]5[Li(THF)2]3 Cluster
  Journal of the American Chemical Society. Mar, 2011  |   Pubmed ID: 21302926
• Sn[Si(SiMe3)3]3- and Sn3[Si(SiMe3)3]4: First Insight into the Mechanism of the Disproportionation of a Tin Monohalide Gives Access to the Shortest Double Bond of Tin
  Chemical Communications (Cambridge, England). Sep, 2010  |   Pubmed ID: 20717582
• The Formation of a Metalloid Sn(10)[Si(SiMe(3))(3)](6) Cluster Compound and Its Relation to the Alpha<-->beta Tin Phase Transition
  Dalton Transactions (Cambridge, England : 2003). Feb, 2010  |   Pubmed ID: 20449434
• [Si(SiMe3)3]6Ge18M (M = Zn, Cd, Hg): Neutral Metalloid Cluster Compounds of Germanium As Highly Soluble Building Blocks for Supramolecular Chemistry
  Dalton Transactions (Cambridge, England : 2003). Nov, 2009  |   Pubmed ID: 20449189
• {Ge9R3Cr(CO)5}- and {Ge9R3Cr(CO)3}-: a Metalloid Cluster (Ge9R3-) As a Flexible Ligand in Coordination Chemistry [R=Si(SiMe3)3]
  Chemical Communications (Cambridge, England). Jun, 2009  |   Pubmed ID: 19587915
• [(OtBu)(2)C(6)H(3)](3)Ge(+) a Free Germyl Cation with Aryl Ligands
  Dalton Transactions (Cambridge, England : 2003). Feb, 2009  |   Pubmed ID: 19156269
• Ge(14)[Ge(SiMe(3))(3)](5)Li(3)(THF)(6): the Largest Metalloid Cluster Compound of Germanium: on the Way to Fullerene-like Compounds?
  Chemical Communications (Cambridge, England). Oct, 2008  |   Pubmed ID: 18815711
• Si@Al56[N(2,6-iPr2C6H3)SiMe3]12: the Largest Neutral Metalloid Aluminum Cluster, a Molecular Model for a Silicon-poor Aluminum-silicon Alloy?
  Angewandte Chemie (International Ed. in English). 2008  |   Pubmed ID: 18814152
• [Si(SiMe(3))(3)](6)Ge(18)M (M = Cu, Ag, Au): Metalloid Cluster Compounds As Unusual Building Blocks for a Supramolecular Chemistry
  Dalton Transactions (Cambridge, England : 2003). Sep, 2008  |   Pubmed ID: 18698446
• Ge4Br4[Mn(CO)5]4 and Ge6Br2[Mn(CO)5]6: First Germanium Cluster Compounds Containing Mn(CO)5 Ligands
  Dalton Transactions (Cambridge, England : 2003). Dec, 2007  |   Pubmed ID: 18026588
• [AuGe18{Si(SiMe3)3}6]-: a Soluble Au-Ge Cluster on the Way to a Molecular Cable?
  Angewandte Chemie (International Ed. in English). 2007  |   Pubmed ID: 17579905
• Metalloid Group 14 Cluster Compounds: an Introduction and Perspectives to This Novel Group of Cluster Compounds
  Chemical Society Reviews. May, 2007  |   Pubmed ID: 17471399
• {Ge10Si[Si(SiMe3)3]4(SiMe32)Me}-: a Ge10Si Framework Reveals a Structural Transition Onto Elemental Germanium
  Chemical Communications (Cambridge, England). Jan, 2007  |   Pubmed ID: 17180243
• Na6[Ge10{Fe(CO)4}8]18 THF: a Centaur Polyhedron of Germanium Atoms
  Angewandte Chemie (International Ed. in English). Aug, 2006  |   Pubmed ID: 16847861
• Ge8R6: the Ligands Define the Bonding Situation Within the Cluster Core
  Dalton Transactions (Cambridge, England : 2003). Oct, 2005  |   Pubmed ID: 16193145
• Subvalent Compounds Featuring Direct Metal-metal Bonds: the Zn-Zn Bond in [Cp*2Zn2]
  Angewandte Chemie (International Ed. in English). May, 2005  |   Pubmed ID: 15844126
• Two Metalloid Ga22 Clusters Containing a Novel Ga22 Core with an Icosahedral Ga12 Center
  Chemistry (Weinheim an Der Bergstrasse, Germany). Apr, 2004  |   Pubmed ID: 15079837
• Novel Compounds of Elements of Group 14: Ligand-stabilized Clusters with "naked" Atoms
  Angewandte Chemie (International Ed. in English). Jan, 2004  |   Pubmed ID: 14755694
• Preparation and Precise Structural Determination of a Second Ga84 Cluster Compound. A First Hint for Cluster Doping and Its Fundamental Consequences in the Field of Chemistry and Physics of Nanoscaled Metalloid Cluster Material
  Inorganic Chemistry. Dec, 2003  |   Pubmed ID: 14632487
• [Ge9[Si(SiMe3)3]3]-: a Soluble Polyhedral Ge9 Cluster Stabilized by Only Three Silyl Ligands
  Angewandte Chemie (International Ed. in English). Jun, 2003  |   Pubmed ID: 12813736
• [Ge8[N(SiMe3)2]6]: a Ligand-stabilized Ge Cluster Compound with Formally Zero-valent Ge Atoms
  Angewandte Chemie (International Ed. in English). Feb, 2003  |   Pubmed ID: 12596175
• [Ga22{N(SiMe3)2}10]2-: a Metalloid Cluster Compound with a Variation of the Ga22 Framework
  Angewandte Chemie (International Ed. in English). Jun, 2002  |   Pubmed ID: 19750621
• Metalloid Aluminum and Gallium Clusters: Element Modifications on the Molecular Scale?
  Angewandte Chemie (International Ed. in English). Oct, 2002  |   Pubmed ID: 12370894
• A Ga(8)R(6) Cluster As an Ideal Model for a Metal-Metal Bond? This Work Was Supported by the Deutsche Forschungsgemeinschaft and by the Fonds Der Chemischen Industrie
  Angewandte Chemie (International Ed. in English). Apr, 2001  |   Pubmed ID: 11301437
• Synthesis and Structure of a Ga(84)R(20)(4-) Cluster-A Link Between Metalloid Clusters and Fullerenes? This Work, Which Had Originally Been Submitted to Nature in September 1999 and Has Been Presented in Part in Lectures Since January 2000, Was Supported by the Deutsche Forschungsgemeinschaft and the Fonds Der Chemischen Industrie
  Angewandte Chemie (International Ed. in English). Feb, 2001  |   Pubmed ID: 11241599