Christian M. Frech

Publications

• Alkyne Hydrothiolation Catalyzed by a Dichlorobis(aminophosphine) Complex of Palladium: Selective Formation of Cis-configured Vinyl Thioethers
  Chemistry (Weinheim an Der Bergstrasse, Germany). Jul, 2012  |   Pubmed ID: 22700478
• Cyanation of Aryl Bromides with K4[Fe(CN)6] Catalyzed by Dichloro[bis{1-(dicyclohexylphosphanyl)piperidine}]palladium, a Molecular Source of Nanoparticles, and the Reactions Involved in the Catalyst-deactivation Processes
  Chemistry (Weinheim an Der Bergstrasse, Germany). Mar, 2012  |   Pubmed ID: 22298440
• Negishi Cross-coupling Reactions Catalyzed by an Aminophosphine-based Nickel System: a Reliable and General Applicable Reaction Protocol for the High-yielding Synthesis of Biaryls
  Chemistry (Weinheim an Der Bergstrasse, Germany). Oct, 2011  |   Pubmed ID: 21887715
• Negishi Cross-coupling Reaction Catalyzed by an Aliphatic, Phosphine Based Pincer Complex of Palladium. Biaryl Formation Via Cationic Pincer-type Pd(IV) Intermediates
  Dalton Transactions (Cambridge, England : 2003). Sep, 2011  |   Pubmed ID: 21691648
• Hydrolysis of Ammonia Borane Catalyzed by Aminophosphine-stabilized Precursors of Rhodium Nanoparticles: Ligand Effects and Solvent-controlled Product Formation
  Chemistry (Weinheim an Der Bergstrasse, Germany). Apr, 2011  |   Pubmed ID: 21416514
• [Pd(Cl)2{P(NC5H10)(C6H11)2}2]--a Highly Effective and Extremely Versatile Palladium-based Negishi Catalyst That Efficiently and Reliably Operates at Low Catalyst Loadings
  Chemistry (Weinheim an Der Bergstrasse, Germany). Sep, 2010  |   Pubmed ID: 20715208
• P Csp(3) P and P Csp(2) P Palladium(II) Hydride Pincer Complexes: Small Structural Difference-large Effect on Reactivity
  Chemistry (Weinheim an Der Bergstrasse, Germany). Jun, 2010  |   Pubmed ID: 20455220
• Dichloro-bis(aminophosphine) Complexes of Palladium: Highly Convenient, Reliable and Extremely Active Suzuki-miyaura Catalysts with Excellent Functional Group Tolerance
  Chemistry (Weinheim an Der Bergstrasse, Germany). Apr, 2010  |   Pubmed ID: 20187044
• Facile Synthetic Access to Rhenium(II) Complexes: Activation of Carbon-bromine Bonds by Single-electron Transfer
  Chemistry (Weinheim an Der Bergstrasse, Germany). Feb, 2010  |   Pubmed ID: 20066700
• Pincer-type Heck Catalysts and Mechanisms Based on Pd(IV) Intermediates: a Computational Study
  Chemistry (Weinheim an Der Bergstrasse, Germany). Feb, 2010  |   Pubmed ID: 20024984
• Highly Selective Dehydrogenative Silylation of Alkenes Catalyzed by Rhenium Complexes
  Chemistry (Weinheim an Der Bergstrasse, Germany). 2009  |   Pubmed ID: 19137560
• Rationally Designed Pincer-type Heck Catalysts Bearing Aminophosphine Substituents: Pd IV Intermediates and Palladium Nanoparticles
  Chemistry (Weinheim an Der Bergstrasse, Germany). 2008  |   Pubmed ID: 18618875
• Short, Facile, and High-yielding Synthesis of Extremely Efficient Pincer-type Suzuki Catalysts Bearing Aminophosphine Substituents
  Angewandte Chemie (International Ed. in English). 2007  |   Pubmed ID: 17654471
• Methylene Transfer from SnMe Groups Mediated by a Rhodium(I) Pincer Complex: Sn-C, C-C, and C-H Bond Activation
  Chemistry (Weinheim an Der Bergstrasse, Germany). 2007  |   Pubmed ID: 17610224
• Direct Observation of Reductive Elimination of Methyl Iodide from a Rhodium(III) Pincer Complex: the Importance of Sterics
  Journal of the American Chemical Society. Sep, 2006  |   Pubmed ID: 16984191
• Metal-controlled Reactivity of a Pincer-type, Sigma-coordinated Naphthyl Radical Anion
  Journal of the American Chemical Society. Jun, 2006  |   Pubmed ID: 16734443
• Unprecedented ROMP Activity of Low-valent Rhenium-nitrosyl Complexes: Mechanistic Evaluation of an Electrophilic Olefin Metathesis System
  Chemistry (Weinheim an Der Bergstrasse, Germany). Apr, 2006  |   Pubmed ID: 16456907
• Redox-induced Collapse and Regeneration of a Pincer-type Complex Framework: a Nonplanar Coordination Mode of Palladium(II)
  Angewandte Chemie (International Ed. in English). Mar, 2005  |   Pubmed ID: 15712307