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Chapter 10

Chemische Bindungen: Molekulare Geometrie und Bindungstheorien

Chapter 10

Chemical Bonding: Molecular Geometry and Bonding Theories

VSEPR Theory and the Basic Shapes
Overview of VSEPR Theory Valence shell electron-pair repulsion theory (VSEPR theory) enables us to predict the molecular structure, including approximate …
VSEPR Theory and the Effect of Lone Pairs
Effect of Lone Pairs of Electrons on Molecule Geometry It is important to note that electron-pair geometry around a central atom is not the same …
Predicting Molecular Geometry
VSEPR Theory for Determination of Electron Pair Geometries The following procedure uses VSEPR theory to determine the electron pair geometries and the …
Molecular Shape and Polarity
Dipole Moment of a Molecule Polar covalent bonds connect two atoms with differing electronegativities, leaving one atom with a partial positive charge …
Valence Bond Theory
Overview of Valence Bond Theory Valence bond theory describes a covalent bond as the overlap of half-filled atomic orbitals (each containing a single …
Hybridization of Atomic Orbitals I
The mathematical expression known as the wave function, ψ, contains information about each orbital and the wavelike properties of electrons in an …
Hybridization of Atomic Orbitals II
sp3d and sp3d 2 Hybridization To describe the five bonding orbitals in a trigonal bipyramidal arrangement, we must use five of the valence shell …
Molecular Orbital Theory I
Overview of Molecular Orbital Theory Molecular orbital theory describes the distribution of electrons in molecules in the same way as the distribution of …
Molecular Orbital Theory II
Molecular Orbital Energy Diagrams The relative energy levels of atomic and molecular orbitals are typically shown in a molecular orbital diagram. For a …
Direct Imaging of Laser-driven Ultrafast Molecular Rotation
We present a method for visualizing laser-induced, ultrafast molecular rotational wave packet dynamics. We have developed a new 2-dimensional Coulomb …
Probing the Structure and Dynamics of Interfacial Water with Scanning Tunneling Microscopy and Spectroscopy
Water/solid interfaces are ubiquitous and play a key role in many environmental, biophysical, and technological processes. Resolving the internal …
Excitonic Hamiltonians for Calculating Optical Absorption Spectra and Optoelectronic Properties of Molecular Aggregates and Solids
Rational design of disordered molecular aggregates and solids for optoelectronic applications relies on our ability to predict the properties of such …