< Back to Core

Chapter 2

Thermodynamique et cinétique chimique

Chapter 2

Thermodynamics and Chemical Kinetics

Chemical Reactions
A balanced chemical equation provides the information of chemical formulas of the reactants and products involved in the chemical change. A …
Enthalpy and Heat of Reaction
Combustion, commonly known as burning, is a reaction in which a substance reacts with an oxidizing agent, which in most cases is molecular oxygen, to …
Energetics of Solution Formation
The formation of a solution is an example of a spontaneous process, which is a process that occurs under specified conditions without energy from some …
Entropy and Solvation
The process of surrounding a solute with solvent is called solvation. It involves evenly distributing the solute within the solvent. The rule of thumb for …
Gibbs Free Energy and Thermodynamic Favorability
The spontaneity of a process depends upon the temperature of the system. Phase transitions, for example, will proceed spontaneously in one direction or …
Chemical and Solubility Equilibria
The free energy change associated with dissolving a solute in a liter of solvent is called the free energy of a solution, ΔGsolution. The overall …
Rate Law and Reaction Order
The rate of a reaction is affected by the concentrations of reactants. Rate laws (differential rate laws) or rate equations are mathematical expressions …
Effect of Temperature Change on Reaction Rate
The Arrhenius equation, relates the activation energy and the rate constant, k, for many chemical reactions. In this equation, R is the ideal gas …
Multi-Step Reactions
Chemical reactions often occur in a stepwise fashion involving two or more distinct reactions taking place in a sequence. A balanced equation indicates …
Bond Dissociation Energy and Activation Energy
Bond energy is the energy required to break a bond homolytically. These values are usually expressed in units of kcal/mol or kJ/mol and are referred to as …
Energy Diagrams, Transition States, and Intermediates
Free-energy diagrams, or reaction coordinate diagrams, are graphs showing the energy changes that occur during a chemical reaction. The reaction …
Predicting Reaction Outcomes
Kinetics describes the rate and path by which a reaction occurs. In contrast, thermodynamics deals with state functions and describes the properties, …
Hot Biological Catalysis: Isothermal Titration Calorimetry to Characterize Enzymatic Reactions
Isothermal titration calorimetry (ITC) is a well-described technique that measures the heat released or absorbed during a chemical reaction, using it as …
Temperature-programmed Deoxygenation of Acetic Acid on Molybdenum Carbide Catalysts
Temperature programmed reaction (TPRxn) is a simple yet powerful tool for screening solid catalyst performance at a variety of conditions. A TPRxn system …
Determination of Thermodynamic Properties of Alkaline Earth-liquid Metal Alloys Using the Electromotive Force Technique
A novel electrochemical cell based on a CaF2 solid-state electrolyte has been developed to measure the electromotive force (emf) of binary alkaline …