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Syntese af hypervalente iodonium Alkynyl Triflater om anvendelse af Generering Cyanocarbenes
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Syntese af hypervalente iodonium Alkynyl Triflater om anvendelse af Generering Cyanocarbenes

Article DOI: 10.3791/50886-v • 12:28 min • September 8th, 2013
September 8th, 2013 •
1, 1, 1
1Department of Chemistry and Biochemistry, University of North Carolina at Greensboro

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Heri beskrives syntese, isolation og reaktioner hypervalente iodonium alkynylgrupper triflater (HIATs) med azider at generere cyanocarbenes. Procedurerne kan indebære air-sensitive og kryogene teknikker, herunder kold filtrering under en inert atmosfære. Håndtering og sikkerheden af ​​de syntetiserede forbindelser vil også blive drøftet.

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Kemi iodforbindelser Azider kulbrinter cyklisk Nitriler oniumforbindelser Eksplosive befuldmægtigede kemi (generelt) kemi af forbindelser kemi elementer organiske kemikalier azider carbener cyanider hypervalente forbindelser syntetiske metoder organisk
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