Переходные металлы и координационные комплексы

Transition metals are defined as those elements that have partially filled d orbitals. As shown in Figure 1, the d-block elements in groups 3–12 are …

In most main group element compounds, the valence electrons of the isolated atoms combine to form chemical bonds that satisfy the octet rule. For …

The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain …

For transition metal complexes, the coordination number determines the geometry around the central metal ion. Table 1 compares coordination numbers to …

Isomerism in Complexes Isomers are different chemical species that have the same chemical formula. Structural isomerism of coordination compounds can be …

Isomerism in Complexes Isomers are different chemical species that have the same chemical formula. Transition metal complexes often exist as geometric …

Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which …

Crystal Field Theory To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between …

Tetrahedral Complexes Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of …

Color in Coordination Complexes When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For …