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11.18: 金属固体
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金属固体
 
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11.18: 金属固体

Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.

All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability. Many are very hard and quite strong. Because of their malleability (the ability to deform under pressure or hammering), they do not shatter and, therefore, make useful construction materials. The melting points of the metals vary widely. Mercury is a liquid at room temperature, and the alkali metals melt below 200 °C. Several post-transition metals also have low melting points, whereas the transition metals melt at temperatures above 1000 °C. These differences reflect differences in the strengths of metallic bonding among metals.

Properties of Metallic Solids

Owing to their crystalline structure, metallic solids exhibit few unique properties associated with the structure and have been tabulated in the following table.

Type of Solid Type of Particles Type of Attractions Properties Examples
Metallic Atoms of electropositive elements Metallic bonds shiny, malleable, ductile, conducts heat and electricity well, variable hardness and melting temperature Cu, Fe, Ti, Pb, U

Crystal Structure of Metallic Solids: Close-packing

Solids that are made of identical atoms can have two types of arrangements: square or close-packed (Figure 1). Since close-packing maximizes the overall attractions between atoms and minimizes the total intermolecular energy, the atoms in most metals pack in this manner.

Eq1

Figure 1. Square vs close-packed arrangement.

We find two types of closest packing in simple metallic crystalline structures: hexagonal closest packing (HCP), and cubic closest packing (CCP). Both consist of repeating layers of hexagonally arranged atoms. In both types, a second layer (B) is placed on the first layer (A) so that each atom in the second layer is in contact with three atoms in the first layer. The third layer is positioned in one of two ways.

In HCP, atoms in the third layer are directly above atoms in the first layer (i.e., the third layer is also a type A), and the stacking consists of alternating type A and type B close-packed layers (i.e., ABABAB⋯) (Figure 2a).

In CCP, atoms in the third layer are not above atoms in either of the first two layers (i.e., the third layer is type C), and the stacking consists of alternating type A, type B, and type C close-packed layers (i.e., ABCABCABC) (Figure 2b). Cubic face-centered (FCC) and CCP arrangements are actually the same structures with compact packing of atoms, occupying 74% of the volume.

Eq1

Figure 2. (a) Hexagonal close-packing consists of two alternating layers (ABABAB…). (b) Cubic close-packing consists of three alternating layers (ABCABCABC…).

In both types of packing, each atom contacts six atoms in its own layer, three in the layer above, and three in the layer below. Thus each atom touches 12 near neighbors and therefore has a coordination number of 12.

About two–thirds of all metals crystallize in closest-packed arrays with coordination numbers of 12. Metals that crystallize in an HCP structure include Cd, Co, Li, Mg, Na, and Zn, and metals that crystallize in a CCP structure include Ag, Al, Ca, Cu, Ni, Pb, and Pt.

This text has been adapted from Openstax, Chemistry 2e, Sections 10.5 The Solid State of Matter, and 10.6 Lattice Structures in Crystalline Solids.

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