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JoVE Journal
Chemistry

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访问有价值的配体为支持过渡金属:1,2,3,4,5-五甲基环戊二烯的一种改进,中级规模制备
 
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访问有价值的配体为支持过渡金属:1,2,3,4,5-五甲基环戊二烯的一种改进,中级规模制备

Article DOI: 10.3791/55366-v 09:45 min March 20th, 2017
March 20th, 2017

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Summary

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Click here for the English version.

1,2,3,4,5-五甲基环戊二烯(的Cp * H)的可靠,中间规模制备呈现。为配位体的合成和纯化的订正协议最小化了专门的实验室设备的需要,同时简化反应workups和产物纯化。的Cp * H中的[Cp * MCL 2]的合成中的应用也被描述2复合物(M =钌,铱)。

Tags

化学,发行121中,Cp * H,铱,配体,五甲基环戊二烯,钌,合成,过渡金属
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