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JoVE Journal Chemistry
Facile Preparation of (2
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Facile Preparation of (2

Article DOI: 10.3791/55766-v • 06:46 min • June 21st, 2017
June 21st, 2017 •
1, 1, 2, 1, 1, 1
1College of Materials, Chemistry and Chemical Engineering, Hangzhou Normal University, 2Shijiazhuang Mechanized Infantry Academy

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Den rutheniumkatalyserede olefinering af elektron-mangelfulde alkener med allylacetat er beskrevet her. Ved anvendelse af aminocarbonyl som en direkte gruppe har denne eksterne oxidant-fri protokol høj effektivitet og god stereo- og regioselektivitet, idet der åbnes en ny syntetisk vej til ( Z , E ) -butadienskelet.

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Kemi udgave 124 dienamid olefinering allylacetat ruthenium oxidantfri 1,3-butadien katalyse
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