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JoVE Journal Chemistry
Syntese af en Thiol byggesten for krystallisering af halvledende Gyroidal Metal-svovl rammer
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Syntese af en Thiol byggesten for krystallisering af halvledende Gyroidal Metal-svovl rammer

Article DOI: 10.3791/57455-v • 12:30 min • April 9th, 2018
April 9th, 2018 •
1, 1, 1, 2
1School of Chemical Engineering and Light Industry, Guangdong University of Technology, 2Department of Chemistry, City University of Hong Kong

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Her præsenterer vi et en-pot, overgang-metal-fri syntese af dithioler og thioesters fra aromatiske halogenider og natrium thiomethoxide, efterfulgt af udarbejdelsen af enkelte krystaller af en metal-dithiolene netværk ved hjælp af thiol arter genereret in situ fra den mere stabil og tractable thioester.

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Kemi spørgsmål 134 Thiol syntese porøse materialer halvledere Metal-økologiske rammer Metal Dithiolene stoffer Gyroid
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