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Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes
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Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes

Article DOI: 10.3791/57948-v • 10:10 min • July 28th, 2018
July 28th, 2018 •
1,2, 1, 1, 1, 1, 1, 2, 1, 1, 1,2
1Institut de Chimie Moléculaire de Reims UMR 7312, Université de Reims Champagne Ardenne, 2Institut Charles Gerhardt Montpellier UMR 5253, Ecole Nationale Supérieure de Chimie de Montpellier

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This protocol describes the preparation of elemental lanthanides under inert atmosphere and their application in a selective C-F activation process involving trifluoromethylated benzofulvenes.

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Elemental Lanthanides C-F Activation Trifluoromethylated Benzofulvenes Difluoroalkenes Reduction Chemistry Organic Chemistry Organo-metallic Reactions Anhydrous Tetrahydrofuran Activated Molecular Sieves Schlenk Tube Magnetic Stir Bar PTFE-lined Plastic Screw Cap Schlenk Line
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