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水介质中水溶性钌烯烃置换催化剂的异质化去除与寄主交互作用
Heterogeneous Removal of Water-Soluble Ruthenium Olefin Metathesis Catalyst from Aqueous Media Via Host-Guest Interaction
JoVE Journal
Chemistry
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JoVE Journal Chemistry
Heterogeneous Removal of Water-Soluble Ruthenium Olefin Metathesis Catalyst from Aqueous Media Via Host-Guest Interaction

水介质中水溶性钌烯烃置换催化剂的异质化去除与寄主交互作用

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10:39 min

August 23, 2018

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10:39 min
August 23, 2018

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Summary

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开发了一种可移动的水溶性n-杂环卡宾 (NHC) 配体在水介质中的宿主-来宾相互作用。我们在水中和二氯甲烷中表现出了代表性的烯烃置换反应。通过主-客交互或萃取, 在反应后, 残余钌 (钌) 催化剂的低至 0.14 ppm。

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