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Photogeneration av N-heterocykliska karbener
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Photogeneration av N-heterocykliska karbener: tillämpning i Photoinduced ringa-öppning metates polymerisation

Article DOI: 10.3791/58539-v • 12:19 min • November 29th, 2018
November 29th, 2018 •
1, 1, 1, 2,3, 2,3, 2,3, 4, 4
1ICGM, Université de Montpellier, CNRS, ENSCM, 2Institut de Science des Matériaux de Mulhouse (IS2M UMR 7361 CNRS), Université de Haute-Alsace, 3Université de Strasbourg, 4Laboratoire de Chimie des Polymères Organiques (LCPO UMR 5629 ENSCBP), Université de Bordeaux

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Vi beskriver ett protokoll till photogenerate N-heterocykliska karbener (NHCs) genom UV-bestrålning av ett 2-isopropylthioxanthone/imidazolium tetraphenylborate salt system. Metoder för att karakterisera photoreleased NHC och belysa den fotokemiska mekanismen föreslås. Protokollen för ringa-öppning metates fotopolymerisation i lösning och miniemulsion illustrerar potentialen i detta 2-komponent NHC photogenerating system.

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Kemi fråga 141 Polymer ringa-öppning metates ROMP Karben NHC miniemulsion photoreactor fotolys Fotokemi photoreactivity
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