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Syntese af monodisperse cylindriske nanopartikler via krystallisation-drevet selv-samling af bionedbrydelige blok copolymerer
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Syntese af monodisperse cylindriske nanopartikler via krystallisation-drevet selv-samling af bionedbrydelige blok copolymerer

Article DOI: 10.3791/59772-v • 11:42 min • June 20th, 2019
June 20th, 2019 •
1, 1, 1, 1
1Department of Chemistry, University of Birmingham

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Krystallisation-drevet selv-samling (CDSA) viser den unikke evne til at fremstille cylindriske nanostrukturer af smalle længde fordelinger. Den organocatalyserede ring-åbnings polymerisering af ε-caprolacton og efterfølgende kæde forlængelser af methylmethacrylat og n, n-dimethylacrylamid påvises. En levende CDSA protokol, der producerer hydroxyapatitmonodisperst cylindre op til 500 nm i længden er skitseret.

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Kemi krystallisation-drevet selv-samling ring-åbning polymerisering reversibel addition-fragmentering kæde overførsel polymerisering nedbrydelige polymerer
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