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Journal / Chemistry / Allsidig CO2 transformasjoner i komplekse…
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Chemistry

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JoVE Journal Chemistry
Allsidig CO2 transformasjoner i komplekse produkter
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Allsidig CO2 transformasjoner i komplekse produkter: A One-Pot to-trinns strategi

Article DOI: 10.3791/60348-v • 07:36 min • November 9th, 2019
November 9th, 2019 •
*1,2, *1, 1, 1
1LCC-CNRS, Université de Toulouse, CNRS, 2LISBP, Université de Toulouse, CNRS, INRA, INSA
* These authors contributed equally

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CO2 transformasjoner er gjennomført i en en-pott to-trinns prosedyre for syntese av komplekse molekyler. Den selektive 4 e- reduksjon av co2 med en hydroborane redusere gir en reaktiv og allsidig BIS (boryl) acetal mellomliggende som senere er involvert i kondens reaksjon eller carbene-mediert c-C kopling generasjon.

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Kjemi CO2 en-pott to-trinns 4e- reduksjon hydroboration BIS (boryl) acetal allsidig reaktivitet chiralitet
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