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动态核磁共振波谱线形分析,用于表征手性铼多氢化物配合物的配位球重排
 
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动态核磁共振波谱线形分析,用于表征手性铼多氢化物配合物的配位球重排

Article DOI: 10.3791/64160-v 10:52 min July 27th, 2022
July 27th, 2022

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在一系列温度下收集的NMR波谱的线形分析可指导手性,八坐标,铼(V)多氢化物配合物ReH5(PPh32丁胺)的内配位球原子的重排。线形分析还用于确定这些原子重排的活化参数ΔH‡,ΔS‡和ΔG

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化学,第185期,
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