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Retropinacol / Çapraz pinakol Kavrama Reaksiyonları - 1,2-Asimetrik Diollerin A Katalitik Erişim
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Retropinacol / Çapraz pinakol Kavrama Reaksiyonları - 1,2-Asimetrik Diollerin A Katalitik Erişim

Article DOI: 10.3791/51258-v • 10:12 min • April 4th, 2014
April 4th, 2014 •
1, 1
1Department of Chemistry, Humboldt University of Berlin

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A retropinacol / çapraz bağlama mekanizmasına pinakol göre simetrik olmayan 1,2-diollerin sentezi için yeni bir hesap tarif edilmektedir. Nedeniyle, geleneksel çapraz pinakol kavrama göre bu reaksiyon bir gelişme katalitik çalıştırılmasına elde edilir.

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Chemistry Sayı 86 çapraz pinakol birleştirme reaksiyonları simetrik olmayan 1,2-dioller kataliz titanyum (IV) alkoksit mekanizma aldehitler ketonlar
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