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Retropinacol / Cross-pinacol koblingsreaktioner - en katalytisk Adgang til 1,2-usymmetriske Dioler
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Retropinacol / Cross-pinacol koblingsreaktioner - en katalytisk Adgang til 1,2-usymmetriske Dioler

Article DOI: 10.3791/51258-v • 10:12 min • April 4th, 2014
April 4th, 2014 •
1, 1
1Department of Chemistry, Humboldt University of Berlin

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En hidtil ukendt hensyn til syntesen af ​​usymmetriske 1,2-dioler baseret på en retropinacol / cross-pinacol koblingsmekanisme beskrevet. På grund af den katalytiske udførelse af denne reaktion en betydelig forbedring i forhold til konventionelle cross-pinacol koblinger er opnået.

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Kemi cross-pinacol koblingsreaktioner usymmetriske 1,2-dioler katalyse titan (IV) alkoxider mekanisme aldehyder ketoner
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