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Retropinacol / Cross-pinacol reacciones de acoplamiento - Un acceso catalítica a 1,2-dioles asimétricos

Article DOI: 10.3791/51258-v • 10:12 min • April 4th, 2014
April 4th, 2014 •
1, 1
1Department of Chemistry, Humboldt University of Berlin

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Una novela cuenta para la síntesis de 1,2-dioles simétricos basados ​​en un mecanismo de acoplamiento retropinacol / cruz-pinacol se describe. Debido a la ejecución catalítica de esta reacción una mejora considerable en comparación con los acoplamientos de cruz-pinacol convencionales se consigue.

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Química las reacciones de acoplamiento cruzado pinacol asimétricas 1,2-dioles catálisis de titanio (IV) alcóxidos mecanismo aldehídos cetonas
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