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Journal / Chemistry / Preparación Facile de (2
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JoVE Journal Chemistry
Preparación Facile de (2
A High-throughput-compatible FRET-based Platform for Identification and Characterization of Botulinum Neurotoxin Light Chain Modulators
Journal (Chemistry)
A High-throughput-compatible FRET-based Platform for Identification and Characterization of Botulinum Neurotoxin Light Chain Modulators
3D Printing and In Situ Surface Modification via Type I Photoinitiated Reversible Addition-Fragmentation Chain Transfer Polymerization
Journal (Chemistry)
3D Printing and In Situ Surface Modification via Type I Photoinitiated Reversible Addition-Fragmentation Chain Transfer Polymerization
 
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Preparación Facile de (2

Article DOI: 10.3791/55766-v • 06:46 min • June 21st, 2017
June 21st, 2017 •
1, 1, 2, 1, 1, 1
1College of Materials, Chemistry and Chemical Engineering, Hangzhou Normal University, 2Shijiazhuang Mechanized Infantry Academy

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Aquí se describe la olefinación catalizada por rutenio de alquenos deficientes en electrones con acetato de alilo. Mediante el uso de aminocarbonilo como grupo directivo, este protocolo exento de oxidante externo tiene una alta eficiencia y buena estereo- y regioselectividad, abriendo una nueva ruta sintética a los esqueletos ( Z , E ) -butadieno.

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Química Edición 124 dienamida olefinación acetato de alilo rutenio libre de oxidante 1,3-butadieno catálisis
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