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Un protocolo de dos etapas para funcionalización de Umpolung de cetonas vía Enolonium especies
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Un protocolo de dos etapas para funcionalización de Umpolung de cetonas vía Enolonium especies

Article DOI: 10.3791/57916-v • 08:12 min • August 16th, 2018
August 16th, 2018 •
1, 1, 1, 1, 1, 1, 1
1Department of Chemical Sciences, Ariel University

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Se describe un protocolo de dos pasos una olla de umpolung de enolatos de cetonas a las especies enolonium y adición de un nucleófilo a la α-posición. Nucleófilos incluyen cloruro, azida, azoles, alil-silanes y compuestos aromáticos.

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Química número 138 Umpolung enolatos de cetonas especies enolonium cetonas allylation aminación
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