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JoVE Journal
Chemistry

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水介质中水溶性钌烯烃置换催化剂的异质化去除与寄主交互作用
 
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水介质中水溶性钌烯烃置换催化剂的异质化去除与寄主交互作用

Article DOI: 10.3791/58067-v 10:39 min August 23rd, 2018
August 23rd, 2018

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Summary

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开发了一种可移动的水溶性n-杂环卡宾 (NHC) 配体在水介质中的宿主-来宾相互作用。我们在水中和二氯甲烷中表现出了代表性的烯烃置换反应。通过主-客交互或萃取, 在反应后, 残余钌 (钌) 催化剂的低至 0.14 ppm。

Tags

化学 问题 138 宿客互动 水溶性 均质催化 异质去除 催化剂去除 置换
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