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Journal / Chemistry / 分离游离卡本内斯、其混合二聚体和有机自由基…
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分离游离卡本内斯、其混合二聚体和有机自由基
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分离游离卡本内斯、其混合二聚体和有机自由基

Article DOI: 10.3791/59389-v • 10:44 min • April 19th, 2019
April 19th, 2019 •
1, 1, 1
1Department of Chemistry and Pharmacy, Friedrich-Alexander-Universität Erlangen-Nürnberg

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我们提出了分离稳定的杂环卡本的方案。利用滤器插管和施伦克技术, 研究了一种循环 (烷基) (氨基) 卡本 (caac) 和n-杂环卡本 (nhc) 的合成方法。此外, 我们还提出了合成相关的氧敏感, 富含电子的混合 "Wanzlick 二聚体" 和减少稳定的有机自由基。

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化学 第146期 化学 卡本斯 n-杂化环卡本 NHC 循环 (烷基) 卡本 CAAC 滤器插管 Schlenk 技术 空气敏感 Wanzlick 的平衡 有机自由 富含电子的烯烃
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