Name: tracking ph during acid-base titration
Uploaded: 2020-09-24T15:06:53.000Z
Duration: 2 min 23 s
Channel: JoVE

K12 Standards

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Ohio’s Learning Standards and Model Curriculum

9-12

Chemistry

Interactions Of Matter

Chemical reactions

Acid-Base Titration Curves

معايرة الحمض والقاعدة،يمكن اجراؤها لتحديد تركيز غير معروف لحمض معين باستخدام تركيز معروف لقاعدة معينة،والعكس صحيح. عند معايرة حمض مع قاعدة،يُضاف المعايِر إلى الحمض تدريجيًا،فيرفع درجة الحموضة pH. توضع الحموضة pH في رسم بياني مقابل كمية القاعدة،لإنشاء منحنى معايرة أو حموضة.تكون منحنيات المعايرة على شكل S،مع وجود فروق تعتمد على كون الحمض قويًا أو ضعيفًا. ستكون pH عند بدء المعايرة حمضية لكنها تكون أعلى في الحمض الضعيف،على فرض أن تركيزات الحمض الأولية تكون متساوية. نقطة التكافؤ،هي النقطة على منحنى المعايرة،التي تتساوى عندها مولات القاعدة مع مولات الحمض في المحلول.في حالة الحمض القوي،تتحقق نقطة التكافؤ عندما تقوم قاعدة قوية بتحييد جميع أيونات الهيدرونيوم التي يُنتجها الحمض القوي،لذلك فإنها تحدث دائمًا عندما تكون درجة pH تساوي 7. وعلى العكس،تتحقق نقطة التكافؤ في الحمض الضعيف عندما تكون pH أكبر من 7 وتتحقق عندما تتحول كل كمية الحمض الضعيف إلى قاعدة مرافقة. قبيل الوصول إلى نقطة التكافؤ،تحدث قفزة مفاجئة في قيمة pH في المحلول.ولكن في معايرة حمض ضعيف،هذه النقلة السريعة في قيمة pH لا تكون حادة كما في معايرة حمض قوي. قيمة pH،بعد نقطة التكافؤ على منحنى المعايرة،سواء كان الحمض قويًا أو ضعيفًا،ترتفع تدريجيًا،وذلك نتيجة القوة المفرطة للقاعدة. ومن الخصائص الأخرى لمنحنى معايرة الحمض الضعيف،لكن ليس القوي،هي المنطقة العازلة ونقط نصف-التكافؤ.عند إضافة قاعدة قوية لحمض ضعيف،فإنه يُنتج قاعدته المرافقة فيكون عازل. تقع نقطة نصف-التكافؤ ضمن هذه المنطقة العازلة. تكون هذه النقطة بعد إضافة نصف كمية القاعدة اللازمة للوصول إلى نقطة التكافؤ.هنا يكون تركيز الحمض الضعيف مساويًا لتركيز قاعدته المرافقة،وتكون درجة pH في المحلول مساوية لـ pKa. منحنيات المعايرة لقاعدة قوية أو ضعيفة،حين يكون المعاير حمضاًقويًا،تشبه حرف S مقلوب،حيث تكون pH مرتفعة في البداية وتنخفض تدريجيًا بإضافة الحمض القوي.

<ol>
	<li>راميت ، ريتشارد دبليو "المعايرة بالتحليل الحجمي: أداة تعليمية لمعايرة المعايرة بالتحليل الحجمي الحمضي". (1994): 238. <a href = "https://pubs.acs.org/doi/pdf/10.1021/ed071p238.2">https://pubs.acs.org/doi/pdf/10.1021/ed071p238.2</a></li>
</ol>

منحنيات معايرة القاعدة الحمضية

يعتبر منحنى المعايرة بالتحليل الحجمي مخططًا لبعض خصائص المحلول مقابل كمية المعايرة المضافة. بالنسبة لمعايرة حمض-قاعدة، يعتبر الرقم الهيدروجيني للمحلول خاصية مفيدة للمراقبة لأنها تختلف بشكل متوقع مع تركيبة المحلول، وبالتالي، يمكن استخدامها لرصد تقدم المعايرة’ واكتشاف نقطة نهايتها. يمكن إجراء معايرة القاعدة الحمضية بحمض قوي وقاعدة قوية، وحمض قوي وقاعدة ضعيفة، أو قاعدة قوية وحمض ضعيف. بالنسبة للمعايرة التي تم إجراؤها لـ 25.00 مل من 0.100 مول HCl (حمض قوي) مع 0.100 مول من NaOH قاعدة قوية، يمكن رؤية منحنى المعايرة باللون الأحمر في الشكل 1 أ. بالنسبة للمعايرة التي تم إجراؤها لـ 25.00 مل من 0.100 مول CH3COOH (حمض ضعيف) مع 0.100 مول NaOH، يمكن رؤية منحنى المعايرة باللون الأصفر في الشكل 1 ب. < / ص> <img alt="Image1" src="/files/ftp_upload/11453/11453_Image_1v2.png" style="text-align: center; height: 350px;" /> الشكل 1 (أ) يحتوي منحنى المعايرة للمعايرة بمقدار 25.00 مل من 0.100 مول HCl (حمض قوي) مع 0.100 مول NaOH (قاعدة قوية) على نقطة تكافؤ قدرها 7.00 رقم هيدروجيني (pH). (ب) يحتوي منحنى المعايرة للمعايرة بمقدار 25.00 مل من حمض أسيتيك 0.100 مول (حمض ضعيف) مع 0.100 مول هيدروكسيد الصوديوم (قاعدة قوية) على نقطة تكافؤ تبلغ 8.72 رقم هيدروجيني (pH). المعايرة لقاعدة قوية أو ضعيفة بحمض قوي لها منحنى مماثل على شكل حرف S؛ ومع ذلك، ينقلب المنحنى حيث يبدأ الأس الهيدروجيني في المنطقة الأساسية وينخفض ​​مع إضافة الحمض القوي. يمكن أيضًا استخدام معايرة الحمض الضعيف أو القاعدة لتحديد Ka أو Kb، على التوالي. المراحل الأربع للمعايرة بالتحليل الحجمي: <ol> <li> الحالة الأولية (حجم المعايرة المضافة = 0 مل): يتم تحديد الأس الهيدروجيني بواسطة الحمض الذي يتم معايرته ؛ نظرًا لأن العينات الحمضية مركزة بشكل متساوٍ، فإن الحمض الضعيف سيُظهر درجة حموضة أولية أكبر </li> <li> نقطة التكافؤ المسبق (0 مل < V < 25 مل): يزداد الرقم الهيدروجيني للمحلول تدريجيًا ويستهلك الحمض بالتفاعل مع محلول معاير مضاف؛ تشتمل التركيبة على حمض غير متفاعل ومنتج التفاعل وقاعدته المترافقة </li> <li> نقطة التكافؤ (V = 25 مل): لوحظ ارتفاع حاد في الرقم الهيدروجيني عندما ينتقل تكوين المحلول من حامضي إلى محايد (لعينة الحمض القوية) أو قاعدي (لعينة الحمض الضعيف)، مع تحديد الرقم الهيدروجيني بواسطة تأين القاعدة المترافقة للحمض </li> <li> نقطة ما بعد التكافؤ (V&#62؛ 25 مل): يتم تحديد الرقم الهيدروجيني من خلال مقدار الزيادة في المعايرة الأساسية القوية المضافة ؛ نظرًا لأن كلا العينتين تمت معايرتهما بنفس المعاير، فإن كلا منحني المعايرة يظهران متشابهين في هذه المرحلة. </li> </ol> هذا النص مقتبس من<a href="https://openstax.org/books/chemistry-2e/pages/14-7-acid-base-titrations"> Openstax, Chemistry 2e, Section 14.7: Acid-base Titrations.</a>

منحنى المعايرة بالتحليل الحجمي هو مخطط لبعض خصائص الحل مقابل كمية المعايرة المضافة. بالنسبة للمعايرة بالتحليل الحجمي الحمضي القاعدي ، يعد الرقم الهيدروجيني للمحلول خاصية مفيدة ل ...

Education

JoVE Core

الكيمياء

واحد

Acid-base and Solubility Equilibria

اتزان الحموض والقواعد والذوبانية

KEY TERMS AND CONCEPTS

المصطلحات والمفاهيم الأساسية

tracking ph during acid-base titration

Acid-base titration uses pH changes to track how a solution responds as titrant is added. A titration curve is a graph of a solution property versus the amount of added titrant. In acid-base titrations, pH is the main property to follow because it changes in a predictable way with the solution makeup and helps show the endpoint.

This pattern can be seen with a strong acid and strong base, a strong acid and weak base, or a strong base and weak acid. For example, 25.00 mL of 0.100 M HCl titrated with 0.100 M NaOH gives one curve, while 25.00 mL of 0.100 M acetic acid titrated with 0.100 M NaOH gives another. The strong acid curve reaches an equivalence point at pH 7.00, while the weak acid curve reaches an equivalence point at pH 8.72.

A titration of a base with a strong acid follows a similar S-shaped pattern, but the curve is flipped. The pH starts in the basic region and drops as the strong acid is added. Weak acids and weak bases can also be used to find Ka or Kb, respectively.

The first stage is the initial state, when no titrant has been added. The pH depends on the acid being titrated. Because the two acid samples in the example have the same concentration, the weak acid starts at a higher pH than the strong acid.

The next stage is the pre-equivalence point, which is 0 mL 25 mL, the pH is set by the extra strong base that has been added. Since both example solutions are titrated with the same base, their curves look similar in this final stage.

Tracking pH During Acid-Base Titration

common ion effect

Common Ion Effect on Solubility

The common ion effect reduces the solubility of an ionic compound in a solution that already contains one of its ions. In aqueous solutions, this means less of the solid dissolves than it would in pure water. The effect follows the law of mass action and can be explained with Le Châtelier’s principle. Silver iodide shows this equilibrium clearly. When silver(I) ions or iodide ions are added, the dissolution equilibrium shifts left. More AgI precipitates, and the concentrations of dissolved Ag+...

buffers

Buffer Solutions and pH Stability

Buffer solutions are mixtures that help keep pH steady. A buffer contains an appreciable amount of a weak conjugate acid-base pair. It resists a change in pH when small amounts of a strong acid or a strong base are added. One common buffer uses a weak acid and its salt. Acetic acid and sodium acetate form this type of system, written as CH3COOH(aq) + CH3COONa(aq). Another buffer uses a weak base and its salt. A solution of ammonia and ammonium chloride, NH3(aq) + NH4Cl(aq), is an example. The...

calculating ph changes in a buffer solution

calculating-ph-changes-in-a-buffer-solution

Buffer pH After Acid or Base Addition

A buffer solution can resist sudden pH changes when a strong acid or strong base is added. It does not stop the pH from changing completely. The shift is usually small, as long as the addition stays within the buffer’s capacity. To find the new pH, first determine how the added acid or base changes the amounts of the buffer components. A buffer contains a weak acid and its conjugate base, or the reverse pair. These amounts are found with stoichiometric calculations, which track how much of...

buffer effectiveness

Buffer Capacity and pH Stability

Buffer solutions help keep pH fairly constant, but they do not work forever. Their resistance to pH change depends on having enough of a weak acid and its conjugate base, or a weak base and its conjugate acid, in the mixture. When too much strong acid or strong base is added, one part of the buffer pair is used up and the buffer action becomes weaker. Buffer capacity describes how much acid or base can be added to a fixed volume of buffer before the pH changes noticeably, usually by about one...

titration calculations: strong acid - strong base

titration-calculations-strong-acid-strong-base

pH at Key Points in Acid-Base Titration

pH at key points in a strong acid and strong base titration can be calculated from the amounts of acid and base present. The example uses 25.00 mL of 0.100 M HCl, a strong acid, and 0.100 M NaOH, a strong base. The pH changes as base is added, and each stage follows a different calculation. At 0 mL of titrant, the pH comes from the ionization of HCl. Because HCl is a strong acid, its ionization is complete. The hydronium ion molarity is 0.100 M, and the pH is found from that value. At 12.50...

titration calculations: weak acid - strong base

titration-calculations-weak-acid-strong-base

pH at Key Points in a Weak Acid Titration

pH at key points in a weak acid titration can be calculated for an acetic acid solution as sodium hydroxide is added. The example uses 25.00 mL of 0.100 M CH3CO2H titrated with 0.100 M NaOH. The reaction is shown as the weak acid reacts with the strong base. The initial pH is found from the acetic acid solution using the usual ICE approach. ICE means initial, change, and equilibrium, and it is a common way to set up equilibrium problems. The solution pH is calculated before any titrant is...

indicators

Acid-Base Color Changes

Acid-base indicators show color changes that help identify the pH of a solution. These are often weak organic acids or weak organic bases, and they respond to changes in hydronium ion concentration in dilute aqueous solution. Phenolphthalein is one example. It is colorless when the hydronium ion concentration is greater than 5.0 × 10^-9 M, which means the pH is below 8.3. In more basic solutions, where the hydronium ion concentration is lower, it turns red or pink. Methyl orange shows how an...

titration of a polyprotic acid

Polyprotic Acid Equivalence Points

Polyprotic acids have more than one ionizable hydrogen, so they lose protons in steps during titration. When the acid dissociation constants for those protons are far enough apart, the titration curve shows a separate equivalence point for each hydrogen that can ionize. Diprotic acids have two ionizable hydrogens and produce two equivalence points. Triprotic acids have three ionizable hydrogens and produce three equivalence points. Carbonic acid, H2CO3, is a weak diprotic acid. Carbonic acid...

solubility equilibria

Predicting Precipitation with Ksp

Solubility equilibria explain how a dissolved ionic compound and its solid form can exist in balance. In a saturated solution, the solute dissolves and the ions precipitate at equal rates. These ideas matter in real settings such as tooth decay and water purification, where compound solubility affects the outcome. A substance with finite solubility can form a saturated solution when more solute is added than the solvent can dissolve. The result is a heterogeneous mixture of the saturated...

factors affecting solubility

Common Ion Effects on Solubility

The common ion effect lowers the solubility of an ionic compound in water when the solution already contains one of the ions made by that compound. It follows the law of mass action and can be explained with Le Châtelier’s principle. When a common ion is added, the dissolution equilibrium shifts toward the solid, so less of the salt stays dissolved. Silver iodide shows this effect clearly. If silver ions or iodide ions are added to a solution of AgI, the equilibrium shifts left and more AgI...

formation of complex ions

Ligands and Complex Ion Stability

Complex ions form when a central atom, often a transition metal cation, binds to ligands. Ligands are ions or molecules around the metal ion. They can be neutral molecules such as H2O or NH3, or ions such as CN− or OH−. In many cases, the ligands act as Lewis bases by donating a pair of electrons to the central atom. These reactions are part of coordination chemistry, which studies coordination complexes. When a metal ion reacts with one or more ligands to form a complex, the equilibrium...

precipitation of ions

Solubility Limits and Selective Precipitation

Solubility limits and selective precipitation explain when ions form a solid in water. The key idea is the balance between an insoluble compound and its dissolved ions. In aqueous solutions that contain calcium ions and carbonate ions, this equilibrium can exist even if the solution was not made by saturating water with calcium carbonate. When two soluble salts are mixed, such as sodium carbonate and calcium nitrate, the ion concentrations determine whether a precipitate forms. If the reaction...

qualitative analysis

Cation Identification by Precipitation Tests

Cation identification by precipitation tests uses selective reactions to find metal ions in a mixture. In qualitative analysis, different reagents are added step by step. Each reaction can produce a characteristic precipitate for a specific group of cations. Other steps, such as changing pH, heating the mixture to dissolve a precipitate again, or adding reagents that form complex ions, help separate ions within the same group. Group IV cations such as Ba2+, Ca2+, and Mg2+ are identified...

henderson-hasselbalch equation

Buffer pH with the Henderson-Hasselbalch Equation

The Henderson-Hasselbalch equation helps relate buffer pH to the weak acid in the solution. It comes from the ionization-constant expression for a weak acid. By rearranging that expression to solve for hydronium ion concentration, [H3O+], and then taking the negative logarithm of both sides, the equation can be written in terms of pH. In this form, pKa is defined as the negative logarithm of the weak acid ionization constant, or pKa = −log Ka. The equation shows the connection between pH, pKa,...

acid-base titration curves

Acid-base titration uses pH changes to track how a solution responds as titrant is added. A titration curve is a graph of a solution property versus the amount of added titrant. In acid-base titrations, pH is the main property to follow because it changes in a predictable way with the solution makeup and helps show the endpoint. This pattern can be seen with a strong acid and strong base, a strong acid and weak base, or a strong base and weak acid. For example, 25.00 mL of 0.100 M HCl titrated...

key terms and concepts

Learn how pH changes reveal the progress of acid-base titration, from the initial state to the equivalence point and beyond, using strong and weak acid examples.

Tracking pH During Acid-Base Titration | JoVE K12

chemistry

JoVE Core Chemistry brings general chemistry concepts to life using concise and easy-to-understand animated video lessons. Plus, in the scientist-in-action videos, we demonstrate classical and original research experiments performed in today's laboratories worldwide.

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New York State Science Learning Standards

High School

Physical Science

HS. Chemical Reactions

HS-PS1-11.

Chemical Equations

Chemical equations represent the identities and relative quantities of substances involved in a chemical reaction. The substances undergoing reaction are ...

Reaction Stoichiometry

A balanced chemical equation provides a great deal of information in a very succinct format. Chemical formulas provide the identities of the reactants and ...

Limiting Reactant

The relative amounts of reactants and products represented in a balanced chemical equation are often referred to as stoichiometric amounts. However, in ...

Reaction Yield

The theoretical yield of a reaction is the amount of product estimated to form based on the stoichiometry of the balanced chemical equation. The ...

Chemical Reactions in Aqueous Solutions

Chemical substances interact in many different ways. Certain chemical reactions exhibit common patterns of reactivity. Due to the vast number of chemical ...

Precipitation Reactions

In a precipitation reaction, aqueous solutions of soluble salts react to give an insoluble ionic compound &#x2013; the precipitate. The reaction occurs ...

Oxidation-Reduction Reactions

Oxidation&ndash;Reduction Reactions

Earth&rsquo;s atmosphere contains about 20% molecular oxygen, O2, a chemically reactive gas that plays an essential ...

Oxidation Numbers

In redox reactions, the transfer of electrons occurs between reacting species. Electron transfer is described by a hypothetical number called the ...

Acids, Bases and Neutralization Reactions

An acid-base reaction is one in which a hydrogen ion, H+, is transferred from one chemical species to another. Such reactions are of central importance to ...

Synthesis and Decomposition Reactions

Synthesis and decomposition are two types of redox reactions. Synthesis means to make something, whereas decomposition means to break something. The ...

Reaction Rate

The rate of reaction is the change in the amount of a reactant or product per unit time. Reaction rates are therefore determined by measuring the time ...

Measuring Reaction Rates

Polarimetry finds application in chemical kinetics to measure the concentration and reaction kinetics of optically active substances during a chemical ...

Concentration and Rate Law

The rate of a reaction is affected by the concentrations of reactants. Rate laws (differential rate laws) or rate equations are mathematical expressions ...

Determining Order of Reaction

Rate laws describe the relationship between the rate of a chemical reaction and the concentration of its reactants. In a rate law, the rate constant k and ...

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The Integrated Rate Law: The Dependence of Concentration on Time

While the differential rate law relates the rate and concentrations of reactants, a second form of rate law called the integrated rate law relates ...

Half-life of a Reaction

The half-life of a reaction (t1/2) is the time required for one-half of a given amount of reactant to be consumed. In each succeeding half-life, half of ...

Temperature Dependence on Reaction Rate

The Collision Theory
Atoms, molecules, or ions must collide before they can react with each other. Atoms must be close together to form chemical bonds. ...

Arrhenius Plots

The Arrhenius equation relates the activation energy and the rate constant, k, for chemical reactions. In the Arrhenius equation, k = Ae&#8722;Ea/RT, R is ...

Reaction Mechanisms

Chemical reactions often occur in a stepwise fashion, involving two or more distinct reactions taking place in a sequence. A balanced equation indicates ...

Thermochemical Equations

For a chemical reaction (the system) carried out at constant pressure &ndash; with the only work done caused by expansion or contraction &ndash; the ...

Rate-Determining Steps

Relating Reaction Mechanisms
In a multistep reaction mechanism, one of the elementary steps progresses significantly slower than the others. This slowest ...

Constant Pressure Calorimetry

Calorimetry is a technique used to measure the amount of heat involved in a chemical or physical process or to measure the heat transferred to or from a ...

Catalysis

The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed ...

Constant Volume Calorimetry

Calorimeters are useful to determine the heat released or absorbed by a chemical reaction. Coffee cup calorimeters are designed to operate at constant ...

Enzymes

Inside living organisms, enzymes act as catalysts for many biochemical reactions involved in cellular metabolism. The role of enzymes is to reduce the ...

Hess's Law

There are two ways to determine the amount of heat involved in a chemical change: measure it experimentally, or calculate it from other experimentally ...

Energy Basics

Chemical reactions, such as those that occur when you light a match, involve changes in energy as well as matter.

Chemical changes and their accompanying ...

Standard Enthalpy of Formation

Enthalpy changes are typically tabulated for reactions in which both the reactants and products are at the same conditions. A standard state is a commonly ...

First Law of Thermodynamics

Energy Conservation

Energy can be converted from one form into another, but all of the energy present before a change occurs always exists in some form ...

Enthalpies of Reaction

Hess&rsquo;s law can be used to determine the enthalpy change of any reaction if the corresponding enthalpies of formation of the reactants and products ...

Internal Energy

The total of all possible kinds of energy present in a substance is called the internal energy (U), sometimes symbolized as E. Suppose a system with ...

Dynamic Equilibrium

A reversible chemical reaction represents a chemical process that proceeds in both forward (left to right) and reverse (right to left) directions. When ...

Quantifying Heat

Thermal Energy&#160;

Microscopically, thermal energy is the kinetic energy associated with the random motion of atoms and molecules. Temperature is a ...

The Equilibrium Constant

Consider the oxidation of sulfur dioxide:

For a reaction that begins with a mixture of reactants only, the product concentration is initially equal to ...

Quantifying Work

As a system undergoes a change, its internal energy can change, and energy can be transferred from the system to the surroundings, or from the ...

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Homogeneous Equilibria for Gaseous Reactions

Homogeneous Equilibria for Gaseous Reactions
For gas-phase reactions, the equilibrium constant may be expressed in terms of either the molar ...

Enthalpy

Chemists ordinarily use a property known as enthalpy (H) to describe the thermodynamics of chemical and physical processes. Enthalpy is defined as the sum ...

Calculating the Equilibrium Constant

The equilibrium constant for a reaction is calculated from the equilibrium concentrations (or pressures) of its reactants and products. If these ...

Reaction Quotient

The status of a reversible reaction is conveniently assessed by evaluating its reaction quotient (Q). For a reversible reaction described by m A + n B ...

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Relative Strengths of Conjugate Acid-Base Pairs

Br&#248;nsted-Lowry acid-base chemistry is the transfer of protons; thus, logic suggests a relation between the relative strengths of conjugate acid-base ...

Calculating Equilibrium Concentrations

Being able to calculate equilibrium concentrations is essential to many areas of science and technology&#8212;for example, in the formulation and dosing ...

Strong Acid and Base Solutions

A strong acid is a compound that dissociates completely in an aqueous solution and produces a concentration of hydronium ions equal to the initial ...

The Small x Assumption

If a reaction has a small equilibrium constant, the equilibrium position favors the reactants. In such reactions, a negligible change in concentration may ...

Weak Acid Solutions

Few compounds act as strong acids. A far greater number of compounds behave as weak acids and only partially react with water, leaving a large majority of ...

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Le Chatelier's Principle: Changing Concentration

A system at equilibrium is in a state of dynamic balance, with forward and reverse reactions taking place at equal rates. If an equilibrium system is ...

Weak Base Solutions

Some compounds produce hydroxide ions when dissolved by chemically reacting with water molecules. In all cases, these compounds react only partially and ...

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Le Chatelier's Principle: Changing Volume (Pressure)

For gas-phase equilibria, changes in the concentrations of reactants and products can occur with altered volume and pressure. The partial pressure, P, of ...

Mixtures of Acids

The pH of a solution containing an acid can be determined using its acid dissociation constant and its initial concentration. If a solution contains two ...

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Le Chatelier's Principle: Changing Temperature

Consistent with the law of mass action, an equilibrium stressed by a change in concentration will shift to re-establish equilibrium without any change in ...

Ions as Acids and Bases

Salts with Acidic Ions
Salts are ionic compounds composed of cations and anions, either of which may be capable of undergoing an acid or base ionization ...

Bronsted-Lowry Acids and Bases

The acid-base reaction class has been studied for quite some time. In 1680, Robert Boyle reported traits of acid solutions that included their ability to ...

Determining the pH of Salt Solutions

The pH of a salt solution is determined by its component anions and cations. Salts that contain pH-neutral anions and the hydronium ion-producing cations ...

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Acid/Base Strengths and Dissociation Constants

The relative strength of an acid or base is the extent to which it ionizes when dissolved in water. If the ionization reaction is essentially complete, ...

Polyprotic Acids

Acids are classified by the number of protons per molecule that they can give up in a reaction. Acids such as HCl, HNO3, and HCN that contain one ...

Water: A Bronsted-Lowry Acid and Base

The reaction between a Br&#248;nsted-Lowry acid and water is called acid ionization. For example, when hydrogen fluoride dissolves in water and ionizes, ...

Acid Strength and Molecular Structure

Binary Acids and Bases
In the absence of any leveling effect, the acid strength of binary compounds of hydrogen with nonmetals (A) increases as the H-A ...

Chemical reactions
• Types of reactions
• Kinetics
• Energy
• Equilibrium
• Acids/bases

Content elaboration: In the Physical Science course, coefficients were used to balance simple equations. Other representations, including Lewis structures and three-dimensional models, were also used and manipulated to demonstrate the conservation of matter in chemical reactions. In this course, more complex reactions will be studied, classified and represented with balanced chemical equations and three-dimensional models. Classifying reactions into types can be a helpful organizational tool for recognizing patterns of what may happen when two substances are mixed. Teachers should be aware that the common reaction classifications that are often used in high school chemistry courses may lead to misconceptions because they are not based on the actual chemistry, but on surface features that can be similar from one system to another (e.g., exchanging partners), even though the underlying chemistry is not the same. However, these classifications may be useful in making predictions about what happens when two substances are mixed. Some general types of chemical reactions are oxidation/reduction, synthesis, decomposition, single replacement, double replacement (including precipitation reactions and some acid-base neutralizations) and combustion reactions. Some reactions can fit into more than one category. For example, a single replacement reaction can also be classified as an oxidation/reduction reaction. Identification of reactions involving oxidation and reduction as well as indicating what substance is being oxidized and what is being reduced are appropriate in this course. However, balancing complex oxidation/reduction reactions is reserved for more advanced study. Organic molecules release energy when undergoing combustion reactions and are used to meet the energy needs of society (e.g., oil, gasoline, natural gas) and to provide the energy needs of biological organisms (e.g., cellular respiration). When a reaction between two ionic compounds in aqueous solution results in the formation of a precipitate or molecular compound, the reaction often occurs because the new ionic or covalent bonds are stronger than the original ion-dipole interactions of the ions in solution. Laboratory experiences (3-D or virtual) with different types of chemical reactions should be provided. Reactions occur when reacting particles collide in an appropriate orientation and with sufficient energy. The rate of a chemical reaction is the change in the amount of the reactants or products in a specific period of time. Increasing the probability or effectiveness of the collisions between the particles increases the rate of the reaction. Therefore, changing the concentration of the reactants, changing the temperature or the pressure of gaseous reactants, or using a catalyst, can change the reaction rate. Likewise, the collision theory can be applied to dissolving solids in a liquid solvent and can be used to explain why reactions are more likely to occur between reactants in the aqueous or gaseous state than between solids. The rate at which a substance dissolves should not be confused with the amount of solute that can dissolve in a given amount of solvent (solubility). Mathematical treatment of reaction rates is reserved for more advanced study. Computer simulations can help visualize reactions from the perspective of the kinetic-molecular theory. In middle school, the differences between potential and kinetic energy and the particle nature of thermal energy were introduced. For chemical systems, potential energy is in the form of chemical energy and kinetic energy is in the form of thermal energy. The total amount of chemical energy and/or thermal energy in a system is impossible to measure. However, the energy change of a system can be calculated from measurements (mass and change in temperature) from calorimetry experiments in the laboratory. Conservation of energy is an important component of calorimetry equations. Thermal energy is the energy of a system due to the movement of its particles. The thermal energy of an object depends upon the temperature and chemical composition. Some materials require little energy to change their temperature and other materials require a great deal to change their temperature by the same amount. Specific heat is a measure of how much energy is needed to change the temperature of a specific mass of material a specific amount. Specific heat values can be used to calculate the thermal energy change, the temperature (initial, final or change in) or mass of a material in calorimetry. Water has a particularly high specific heat capacity, which is important in regulating Earth's temperature. As studied in middle school, chemical energy is the potential energy associated with chemical systems. Chemical reactions involve valence electrons forming bonds to yield more stable products with lower energies. Energy is required to break interactions and bonds between the reactant atoms and energy is released when an interaction or bond is formed between the atoms in the products. Molecules with weak bonds (e.g., ATP) are less stable and tend to react to produce more stable products, releasing energy in the process. Generally, energy is transferred out of the system (exothermic) when the products have stronger bonds than the reactants and is transferred into the system (endothermic) when the reactants have stronger bonds than the products. Predictions of the energy requirements (endothermic or exothermic) of a reaction can be made given a table of bond energies. Graphic representations can be drawn and interpreted to represent the energy changes during a reaction. The role of energy in determining the spontaneity of chemical reactions is dealt with conceptually in this course. Entropy and its influence on the spontaneity of reactions are reserved for more advanced study. All reactions are reversible to a degree and many reactions do not proceed completely toward products but appear to stop progressing before the reactants are all used up. At this point, the amounts of the reactants and the products appear to be constant and the reaction can be said to have reached dynamic equilibrium. Dynamic equilibrium means the rate of the reverse reaction is equal to the rate of the forward reaction so there is no apparent change in the reaction. If a chemical system at equilibrium is disturbed by a change in the conditions of the system (e.g., increase or decrease in the temperature, pressure on gaseous equilibrium systems, concentration of a reactant or product), then the equilibrium system will respond by shifting to a new equilibrium state, reducing the effect of the change (Le Chatelier's Principle). If products are removed as they are formed during a reaction, then the equilibrium position of the system is forced to shift to favor the products. In this way, an otherwise unfavorable reaction can be made to occur. Mathematical treatment of equilibrium reactions is reserved for advanced study. Computer simulations can help visualize the progression of a reaction to dynamic equilibrium and the continuation of both the forward and reverse reactions after equilibrium has been attained. Properties of acids and bases and the ranges of the pH scale were introduced in Physical Science. In this course, the structural features of molecules are explored to further understand acids and bases. Acids often result when hydrogen is covalently bonded to an electronegative element and is easily dissociated from the rest of the molecule to bind with water to form a hydronium ion (H3O+). The acidity of an aqueous solution can be expressed as pH, where pH can be calculated from the concentration of the hydronium ion. Bases are likely to dissociate in water to form a hydroxide ion. Acids can react with bases to form a salt and water. Such neutralization reactions can be studied quantitatively by performing titration experiments.

Tracking pH During Acid-Base Titration

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