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Principles of Nuclear Magnetic Resonance
Magnetic Field and Nuclear Precession
Description
Magnetic field strength controls nuclear precession in NMR. A spinning nucleus has a magnetic moment, and that moment turns around an external magnetic field directed along the z-axis. This motion is called Larmor precession, and its angular frequency is the Larmor frequency.
The Larmor frequency...
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Transcript
由于太阳和月球的引力作用,地球的自转轴会在一段时间内发生摆动和变化,这一现象称为岁差。
类似地,自旋原子核的磁矩 μ 会在沿 z 轴方向施加的磁场 B0 作用下发生进动。
此处,进动对应于自旋原子核围绕 B0 场的旋转运动,形成一个圆锥轨迹。
磁矩矢量在磁场中的旋进称为拉莫尔旋进。旋进的角频率 ω,称为旋进频率或拉莫尔频率,与 B0 成正比。
磁旋比 γ 表示角频率 ω 与 B0 之间的比例常数;对于每一种原子核,该值是固定的。
如果将 ω ...
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