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Chemistry

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Analytical Chemistry

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Principles of Nuclear Magnetic Resonance

NMR Pulse Angles and Signal Collection

Description

NMR pulse angles and signal collection explain how radiofrequency energy starts a measurement. A pulse is a short burst of radio waves spread across a range of frequencies. It excites the nuclei in the sample at the same time.

When a radiofrequency pulse is applied along the x-axis, nuclei absorb...

Transcript

脉冲是一段短暂的高功率射频辐射,包含样品中被观测原子核的拉莫尔频率。

当原子核吸收能量时,净磁化矢量会向横向平面偏移。

磁化矢量的这一旋转角度,即翻转角度,与脉冲的持续时间和强度成正比。

90度脉冲将净磁化矢量精确地转向x–y平面,而180度脉冲则将其转向−z方向。

当磁化矢量沿z轴恢复至平衡状态时,在采集时间内收集发射的FID信号。

脉冲序列从发射器发出的激发脉冲开始,随后进入采集时间。

然后通过弛豫延迟,使原子核在下一个脉冲施加前完全弛豫并重新建立平衡。

涉及不同核磁共振活性核的实验采用多通道脉冲序列,其中每个通道的频率与一种特定类...