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Chemistry

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Analytical Chemistry

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Electrochemical Analyses and Redox Titration

Redox Titration Endpoints and Indicators

Description

Redox titration uses electron transfer in a redox, or reduction-oxidation, reaction to find the concentration of an unknown solution. The titrant has a known concentration, and it is added gradually to the analyte, which is the solution being tested. The endpoint shows when the reaction between the two substances is complete...

Transcript

氧化还原滴定法用于分析分析物与滴定剂之间发生的氧化还原反应。

分析物通常需要用辅助氧化剂或还原剂进行处理,以将其均匀地转化为滴定所需的单一氧化态。

通过使用电位计或目视指示剂来检测反应的完成情况。

视觉指示剂有三种类型:氧化还原指示剂、淀粉指示剂和自身指示剂。

氧化还原指示剂是一类在氧化态和还原态下呈现明显不同颜色的深色染料。

大多数氧化还原指示剂对滴定过程中电位的变化敏感。将电位对滴定剂体积作图可得到滴定曲线。

氧化还原滴定曲线呈S形,在滴定终点附近电位逐渐上升,直至出现突然的跃升。

淀粉指示剂用于碘滴定中,淀粉与碘结合形成深蓝色复合物。

自身指示剂在氧化还原滴定中也可使用...