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Analytical Chemistry

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Acid–Base Titration

Weak Acid Titration Curve and pH Stages

Description

Weak acid titration with a strong base changes pH in clear stages. The acid in this example is acetic acid, and the base is sodium hydroxide. Each stage uses a different pH calculation method.

At the start, the pH of the weak acid is found with its dissociation constant, Ka, and an ICE table. An ...

Transcript

弱酸与强碱的滴定计算方法因主要反应物的不同而有所差异。

最初,50 mL 的 0.1 M 乙酸溶液的 pH 为 2.87,该值通过 Ka 和 ICE 表计算得出。

用 0.1 M NaOH 滴定后,溶液形成缓冲液。

加入 10 mL NaOH 可生成 0.001 摩尔乙酸根,剩余 0.004 摩尔乙酸。根据 Henderson-Hasselbalch 方程计算,所得 pH 值为 4.14。

反应进行到一半时,由于乙酸与乙酸根离子浓度相等,pH 等于 pKa

在等当点时,加入 50 mL NaOH 可将所有乙酸完全转化为乙酸根,导致 pH...

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