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Inorganic Chemistry

Geometry of Ni and Pd dppf Complexes

Description

Nickel and palladium dppf complexes are the focus of this chemistry protocol. It guides the synthesis of two metal complexes that contain the ligand 1,1'-bis(diphenylphosphino)ferrocene, or dppf. The compounds are M(dppf)Cl2, where M is Ni or Pd.

Both metal complexes are four-coordinate, meaning ...

Transcript

ืชื•ืจืช ื”ืื•ืจื‘ื™ื˜ืœื™ื ื”ืžื•ืœืงื•ืœืจื™ื™ื ื”ื™ื ืžื•ื“ืœ ื’ืžื™ืฉ ืœืชื™ืื•ืจ ื”ืชื ื”ื’ื•ืช ืืœืงื˜ืจื•ื ื™ื ื‘ืงื•ืžืคืœืงืกื™ื ืฉืœ ืงื‘ื•ืฆื” ืจืืฉื™ืช ื•ืžืชื›ื•ืช ืžืขื‘ืจ.

ื ื™ืชืŸ ืœื™ื™ืฆื’ ืงืฉืจื™ื ื›ื™ืžื™ื™ื ื•ื”ืชื ื”ื’ื•ืช ืืœืงื˜ืจื•ื ื™ืช ื‘ืžืกืคืจ ืกื•ื’ื™ื ืฉืœ ื“ื’ืžื™ื. ื‘ืขื•ื“ ืฉืžื•ื“ืœื™ื ืคืฉื•ื˜ื™ื, ื›ื’ื•ืŸ ืžื‘ื ื™ ื ืงื•ื“ื•ืช ืœื•ืื™ืก ื•ืชื•ืจืช VSEPR, ืžืกืคืงื™ื ื ืงื•ื“ืช ื”ืชื—ืœื” ื˜ื•ื‘ื” ืœื”ื‘ื ืช ืชื’ื•ื‘ืชื™ื•ืช ืžื•ืœืงื•ืœืจื™ืช, ื”ื ื›ื•ืœืœื™ื ื”ื ื—ื•ืช ืจื—ื‘ื•ืช ืœื’ื‘ื™ ื”ืชื ื”ื’ื•ืช ืืœืงื˜ืจื•ื ื™ืช ืฉืœื ืชืžื™ื“ ื™ืฉื™ืžื•ืช <...

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