Name: how energy changes in chemical reactions
Uploaded: 2020-09-03T13:38:27.000Z
Duration: 2 min 27 s
Channel: JoVE

K12 Standards

north-carolina-k-12-science-standard-course-of-study

NC K-12 Science Standard Course of Study

9-12

Chemistry

Energy

PS.Chm.7.2

Energy Basics

Dlaczego sód metaliczny reaguje z wodą, tworząc gazowy wodór, ale chlorek sodu po prostu się rozpuszcza? Można to wyjaśnić, badając związek między chemią a energią, zwany "termochemią".

Wszystkie formy materii są związane z energią, którą można zmierzyć jako ciepło lub pracę. 

Dwa główne rodzaje energii to energia potencjalna i kinetyczna.

Energia potencjalna opisuje siły pozycyjne działające na obiekt. Skała na szczycie wzgórza ma większą energię potencjalną niż skała na dole, ponieważ skała na szczycie znajduje się dalej od środka masy Ziemi.

Energia kinetyczna to energia poruszającego się obiektu. Jeśli skała zostanie zepchnięta ze wzgórza, traci energię potencjalną, ale zyskuje energię kinetyczną podczas ruchu.

Dotyczy to również atomów lub cząsteczek tworzących obiekt. Obiekt w spoczynku nadal ma energię kinetyczną, ponieważ jego atomy składowe mogą wibrować.

Ta forma energii kinetycznej nazywana jest energią cieplną. Obiekt ma wyższą energię kinetyczną, a co za tym idzie wyższą energię cieplną, gdy atomy poruszają się bardziej energicznie. Ten obiekt jest postrzegany jako gorący.

Cząsteczki mają również energię potencjalną zwaną energią chemiczną, która jest związana ze względnym położeniem elektronów i jąder. 

Podczas reakcji energia chemiczna jest przekształcana w inne formy energii, takie jak światło, lub uwalniana jest energia, na przykład w postaci ciepła.

Ilość przekształcanej energii zależy od struktury molekularnej reagentów.

W lampie gazowej acetylen spala się w dwutlenek węgla i wodę, uwalniając dużą ilość energii w postaci światła.

Z drugiej strony, dodanie wodorotlenku sodu do kwasu solnego uwalnia mniejszą ilość energii, jaką jest ciepło.

Aby badać zmiany energii, pomaga podzielić wszechświat na "system", który zawiera obserwowany proces, oraz "otoczenie", które jest wszystkim innym.

System może być otwarty, co oznacza, że zarówno energia, jak i masa mogą być wymieniane między systemem a otoczeniem. System może być zamknięty, w którym wymieniana jest tylko energia, lub system może być odizolowany, gdzie nie dochodzi do wymiany ani masy, ani energii.

podstawy energii

Reakcje chemiczne, takie jak te, które zachodzą podczas zapalania zapałki, obejmują zmiany energii i materii.

Zmiany chemiczne i towarzyszące im zmiany energii są ważnym elementem codziennego życia. Makroelementy w żywności podlegają reakcjom metabolicznym, które dostarczają energii niezbędnej do funkcjonowania organizmu. W celu wytworzenia energii potrzebnej do transportu, ogrzewania i wytwarzania energii elektrycznej spala się różnorodne paliwa (benzyna, gaz ziemny, węgiel). Przemysłowe reakcje chemiczne zużywają ogromne ilości energii do produkcji surowców (takich jak żelazo i aluminium). Energia jest następnie wykorzystywana do produkcji tych surowców w codziennych przedmiotach, takich jak samochody, drapacze chmur i mosty.

Ponad 90% energii wykorzystywanej przez człowieka pochodzi pierwotnie ze słońca. Każdego dnia słońce dostarcza Ziemi prawie 10 000 razy więcej energii potrzebnej do zaspokojenia całego zapotrzebowania energetycznego świata na ten dzień. Wyzwaniem pozostaje znalezienie sposobów przekształcania i magazynowania napływającej energii słonecznej, tak aby można ją było wykorzystać w reakcjach lub procesach chemicznych, które są zarówno wygodne, jak i niezanieczyszczające. Rośliny i wiele bakterii wychwytuje energię słoneczną w procesie fotosyntezy. Ludzie uwalniają energię zmagazynowaną w roślinach podczas spalania drewna, węgla, ropy naftowej lub innych produktów roślinnych, takich jak etanol. Wykorzystują tę energię również do "zasilania" swoich ciał, jedząc żywność pochodzącą bezpośrednio z roślin.

<h4>Termochemia</h4>

Podstawowe idee ważnej dziedziny nauki dotyczącej ilości ciepła pochłoniętego lub uwolnionego podczas przemian chemicznych i fizycznych — nazywa się termochemią. Pojęcia te są szeroko stosowane w prawie wszystkich dziedzinach nauki i techniki. Naukowcy zajmujący się żywnością wykorzystują termochemię do określenia zawartości energetycznej żywności. Biolodzy badają energetykę organizmów żywych, na przykład metaboliczne spalanie cukru do dwutlenku węgla i wody. Przemysł naftowy, gazowy i transportowy, dostawcy energii odnawialnej i wiele innych starają się znaleźć lepsze metody wytwarzania energii na potrzeby komercyjne i osobiste. Inżynierowie starają się między innymi poprawiać efektywność energetyczną, znajdować lepsze sposoby ogrzewania i chłodzenia domów, schładzania żywności i napojów oraz zaspokajania potrzeb w zakresie energii i chłodzenia komputerów i urządzeń elektronicznych. Zrozumienie zasad termochemii jest niezbędne dla chemików, fizyków, biologów, geologów, inżynierów i prawie każdego, kto studiuje lub zajmuje się jakąkolwiek nauką.

<h4>Energia</h4>

Energię można zdefiniować jako zdolność do dostarczenia ciepła lub wykonania pracy. Jednym z rodzajów pracy (w) jest proces powodowania ruchu materii wbrew przeciwnej sile. Na przykład podczas pompowania opony rowerowej materia (powietrze w pompce) porusza się wbrew przeciwnej sile powietrza znajdującego się już w oponie.

Podobnie jak materia, energia występuje w różnych rodzajach. Jeden ze schematów dzieli energię na dwa typy: energię potencjalną, czyli energię obiektu ze względu na jego względne położenie, skład lub stan, oraz energię kinetyczną, czyli energię, którą obiekt posiada ze względu na swój ruch.

Woda na szczycie wodospadu lub tamy ma energię potencjalną ze względu na swoje położenie; przepływając w dół przez generatory, posiada energię kinetyczną, którą można wykorzystać do wykonania pracy i wytworzenia energii elektrycznej w elektrowni wodnej. Bateria ma energię potencjalną, ponieważ zawarte w niej substancje chemiczne mogą wytwarzać energię elektryczną zdolną do wykonania pracy.

Podstawy energii

Reakcje chemiczne, takie jak te, które zachodzą, gdy zapalasz zapałkę, obejmują zmiany zarówno energii, jak i materii.

Zmiany chemiczne i towarzyszące im ...

Education

JoVE Core

Chemia

Jeden

Thermochemistry

Termochemia

KEY TERMS AND CONCEPTS

Kluczowe terminy i pojęcia

how energy changes in chemical reactions

Chemical reactions change matter and energy at the same time. A match lighting is a simple example. These energy changes are part of everyday life and appear in food, fuels, and industry.

Food provides energy through metabolic reactions. The macronutrients in food break down and help keep the body functioning. Fuels such as gasoline, natural gas, and coal are burned to produce energy for transportation, heating, and electricity generation.

Industrial chemical reactions also use large amounts of energy. That energy helps make raw materials like iron and aluminum. More energy is then needed to turn those materials into products such as cars, skyscrapers, and bridges.

Most energy used by humans comes from the sun. Every day, the sun sends Earth almost 10,000 times more energy than the world needs for that day. The challenge is to capture and store solar energy so it can drive chemical processes that are useful, convenient, and nonpolluting.

Plants and many bacteria capture solar energy through photosynthesis. Humans release stored energy by burning wood, coal, petroleum, or plant products such as ethanol. They also use this energy directly when they eat food that comes from plants.

Thermochemistry is the study of heat absorbed or released during chemical and physical changes. It is used to measure the energy content of foods and to study the energetics of living organisms, such as the breakdown of sugar into carbon dioxide and water. It also supports work in the oil, gas, transportation, and renewable energy industries, as well as in engineering.

Energy is the capacity to supply heat or do work. Work means causing matter to move against an opposing force, such as when air is pushed into a bicycle tire. Energy can be described as potential energy, which depends on position, composition, or condition, and kinetic energy, which depends on motion.

A waterfall or dam stores potential energy because of its position. When the water flows downward through generators, it has kinetic energy that can do work and produce electricity in a hydroelectric plant. A battery also stores potential energy because the chemicals inside it can produce electricity when needed.

How Energy Changes in Chemical Reactions

energy basics

Chemical reactions change matter and energy at the same time. A match lighting is a simple example. These energy changes are part of everyday life and appear in food, fuels, and industry. Food provides energy through metabolic reactions. The macronutrients in food break down and help keep the body functioning. Fuels such as gasoline, natural gas, and coal are burned to produce energy for transportation, heating, and electricity generation. Industrial chemical reactions also use large amounts...

first law of thermodynamics

Energy Conservation and Internal Energy

Energy conservation describes how energy changes form during chemical and physical changes. Energy can be converted from one form into another, but the energy present before a change still exists in some form after the change is complete. This is the law of conservation of energy. It says energy can neither be created nor destroyed. The law of conservation of matter also applies during chemical change. In most chemical reactions, the total amount of matter does not show a detectable change.

internal energy

Internal Energy, Heat, and Work

Internal energy is the total of all possible kinds of energy in a substance. It is often written as U, and sometimes as E. For a system that changes energy, the important value is the change in internal energy, or ΔU. ΔU is the difference between the final internal energy and the initial internal energy. The exact values of U final and U initial are usually not known, but the first law of thermodynamics only requires ΔU. A positive ΔU means the system gained energy from the surroundings. A...

quantifying heat

Heat Transfer and Specific Heat

Heat transfer and specific heat explain how thermal energy moves and how materials respond to it. Thermal energy is the kinetic energy linked to the random motion of atoms and molecules. Temperature is a measure of how hot or cold a substance is, and it depends on how much thermal energy those particles have. When atoms and molecules move or vibrate faster, their average kinetic energy is higher. That means the object has more thermal energy and a higher temperature. When they move more...

quantifying work

Pressure-Volume Work in Chemistry

Pressure-volume work shows how gas volume changes can transfer energy in chemistry. As a system changes, its internal energy may change too. Energy can move between the system and the surroundings through heat and work. Internal energy, heat, and work are related by an energy equation. Heat depends on a measured temperature change. Work depends on a measured change in volume called pressure-volume work. Work can be defined as a force acting through a distance. Pressure-volume work, also...

enthalpy

Enthalpy and Heat at Constant Pressure

Enthalpy describes heat changes in chemical and physical processes. Chemists use the symbol H for enthalpy. It is defined as a system’s internal energy, E, plus the product of pressure, P, and volume, V. Enthalpy is a state function, so only changes in enthalpy can be measured, not the enthalpy of a substance by itself. For many reactions, the pressure stays constant. Under those conditions, the enthalpy change, ΔH, can be written in a way that includes pressure-volume work. The term PΔV...

thermochemical equations

Heat Changes in Chemical Equations

Heat changes in chemical equations show how much energy a reaction releases or absorbs. At constant pressure, the enthalpy of reaction, or ΔHrxn, is equal to the heat exchanged with the surroundings, qp. Because this value depends on how much reactant takes part, it is an extensive property. The size and sign of ΔHrxn also depend on the reaction itself and on the physical states of the substances involved. An exothermic reaction has a negative ΔHrxn value, while an endothermic reaction has a...

constant pressure calorimetry

Coffee Cup Calorimeter Heat Changes

Coffee cup calorimetry measures heat changes in reactions and physical changes using an insulated calorimeter. The calorimeter is calibrated and designed to limit heat exchange with the outside environment. That makes it possible to measure the heat taken in or released by a substance more accurately, including the energy content of foods. In calorimetry, the system is the substance or substances undergoing change. The surroundings are everything else inside the calorimeter, including the...

constant volume calorimetry

Bomb Calorimeter Heat Measurement

Bomb calorimetry measures the heat released by reactions that produce a lot of energy, especially combustion reactions. A coffee cup calorimeter works at constant pressure and is useful for reactions in solution. A bomb calorimeter works at constant volume and is used for reactions that make large amounts of heat and gaseous products. The word "bomb" refers to the strong, explosive force some reactions can have. In a bomb calorimeter, the volume does not change, so 94V = 0. That means the...

hess's law

Calculating Reaction Heat with Hess's Law

Calculating reaction heat with Hess's law lets chemists find enthalpy changes without measuring every reaction directly. Some reactions are hard or impossible to test in the lab. Even when a reaction can be measured, it is often easier to calculate the heat change from other known enthalpy values. Hess's law says that if a process can be written as the sum of several stepwise processes, the enthalpy change for the total process equals the sum of the enthalpy changes for the steps. This works...

standard enthalpy of formation

Using Standard Enthalpy Values in Chemistry

Enthalpy changes are often listed for reactions that start and end under the same conditions. Chemists use a standard state as a reference set of conditions for comparing properties. In IUPAC terms, the standard state means 1 bar of pressure and 1 M solutions, but it does not set a temperature. Many thermochemical tables still use 1 atm as the reference pressure. Because the difference between 1 bar and 1 atm is very small, enthalpy change usually stays almost the same. A superscripted o in...

enthalpies of reaction

Calculating reaction heat with Hess's law uses standard enthalpies of formation to find the enthalpy change of a reaction. When the formation values for the reactants and products are known, the overall reaction can be broken into simpler stepwise reactions. This approach helps show how the heat change for the full reaction is built from smaller parts. First, the reactants are thought of as being decomposed into their component elements. The enthalpy change for this step is proportional to the...

key terms and concepts

Explore how chemical reactions change energy in food, fuels, photosynthesis, thermochemistry, and batteries. Built for high school science learners.

How Energy Changes in Chemical Reactions | JoVE K12

chemistry

JoVE Core Chemistry brings general chemistry concepts to life using concise and easy-to-understand animated video lessons. Plus, in the scientist-in-action videos, we demonstrate classical and original research experiments performed in today's laboratories worldwide.

Matter and its Interactions

PS.Chm.4.1

Earth and Environmental Science

Earth's Systems

ESS.EES.3.2

Physical Science

PS.PSc.7.1

Pennsylvania State Academic Standards

3.2.9-12.O

3.2.9-12.P

3.2.9-12.Q

3.2.9-12.R

Louisiana Student Standards for Science

High School

Matter And Its Interactions

HS-PS1-4

HS-PS1-5

HS-PS3-2

HS-PS3-3

HS-PS3-4

Physics

HS-PS3-1

ohios-learning-standards-and-model-curriculum

Ohio’s Learning Standards and Model Curriculum

Study Of Matter

Classification of matter

Energy And Waves

Thermal energy

Interactions Of Matter

Chemical reactions

Physical Geology

Earth's Resources

Energy resources

Tennessee Academic Standards

CHEM1.PS3.3

Virginia  Standards of Learning

HIgh School

CH.7

CH.7.a

Earth Science

ES.6

ES.6.d

Minnesota Academic Standards in Science

3.1.1 9C.2.2.1.1

Texas Essential Knowledge and Skills

CHEM.13

CHEM.13.A

CHEM.13.C

Alabama Course of Study Science

9-12.PS.1.1

Earth and Space Science

Earth's Place in the Universe

9-12.ESS.1.1

9-12.ESS.1.1.a

Next Generation Science Standards

Life Science

from-molecules-to-organisms-structures-and-processes

From Molecules to Organisms: Structures and Processes

HS-LS1-7

Florida Department of Education

SC.912.E.6

SC.912.E.6.6

SC.912.P.10

SC.912.P.10.1

south-carolina-college-and-career-ready-science-standards

South Carolina College and Career Ready Science Standards

Matter and Its Interactions

C-PS1-4

C-PS1-5

C-PS3-4

P-PS3-1

P-PS3-2

P-PS3-3

new-york-state-science-learning-standards

New York State Science Learning Standards

HS. Energy

HS-PS3-1.

Georgia Standards of Excellence

SPS7.

Types of Energy

Classifying Matter by State

Chemistry is the study of matter and the changes it undergoes. Matter is anything that has mass and occupies space. Matter is all around us; the air, ...

Classifying Matter by Composition

Matter: Pure Substances and Mixtures
According to its composition, the matter can be classified into two broad categories &mdash; pure substances and ...

physical-and-chemical-properties-of-matter

Physical and Chemical Properties of Matter

The characteristics that enable us to distinguish one substance from another are called properties.

Physical Properties of Matter

A physical property is ...

molecular-comparison-of-gases-liquids-and-solids

Molecular Comparison of Gases, Liquids, and Solids

Particles in a solid are tightly packed together (fixed shape) and often arranged in a regular pattern; in a liquid, they are close together with no ...

Intermolecular vs Intramolecular Forces

Intermolecular forces (IMF) are electrostatic attractions arising from charge-charge interactions between molecules. The strength of the intermolecular ...

Intermolecular Forces

Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions ...

comparing-intermolecular-forces-melting-point-boiling-point

Comparing Intermolecular Forces: Melting Point, Boiling Point, and Miscibility

Intermolecular forces are attractive forces that exist between molecules. They dictate several bulk properties, such as melting points, boiling points, ...

surface-tension-capillary-action-and-viscosity

Surface Tension, Capillary Action, and Viscosity

Surface Tension
The various IMFs between identical molecules of a substance are examples of cohesive forces. The molecules within a liquid are surrounded ...

States of Matter and Phase Changes

The internal energy of a substance&#8212;the total kinetic energy of all its molecules and the potential energy of their associated forces&#8212;depends ...

Phase Transitions

Whether solid, liquid, or gas, a substance&#39;s state depends on the order and arrangement of its particles (atoms, molecules, or ions). Particles in the ...

phase-transitions-vaporization-and-condensation

Phase Transitions: Vaporization and Condensation

The physical form of a substance changes on changing its temperature. For example, raising the temperature of a liquid causes the liquid to vaporize ...

Vapor Pressure

When a liquid vaporizes in a closed container, gas molecules cannot escape. As these gas phase molecules move randomly about, they will occasionally ...

Clausius-Clapeyron Equation

The equilibrium between a liquid and its vapor depends on the temperature of the system; a rise in temperature causes a corresponding rise in the vapor ...

Phase Transitions: Melting and Freezing

Heating a crystalline solid increases the average energy of its atoms, molecules, or ions, and the solid gets hotter. At some point, the added energy ...

phase-transitions-sublimation-and-deposition

Phase Transitions: Sublimation and Deposition

Some solids can transition directly into the gaseous state, bypassing the liquid state, via a process known as sublimation. At room temperature and ...

Heating and Cooling Curves

When a substance&#8212;isolated from its environment&#8212;is subjected to heat changes, corresponding changes in temperature and phase of the substance ...

Phase Diagrams

A phase diagram combines plots of pressure versus temperature for the liquid-gas, solid-liquid, and solid-gas phase-transition equilibria of a substance. ...

Use models to explain how changes in energy affect the arrangement and movement of the particles in solids, liquids, and gases, as well as the relative strengths of their intermolecular forces.

PS.Chm.7.1

Chemical reactions, such as those that occur when you light a match, involve changes in energy as well as matter.

Chemical changes and their accompanying ...

First Law of Thermodynamics

Energy Conservation

Energy can be converted from one form into another, but all of the energy present before a change occurs always exists in some form ...

Internal Energy

The total of all possible kinds of energy present in a substance is called the internal energy (U), sometimes symbolized as E. Suppose a system with ...

Quantifying Heat

Thermal Energy&#160;

Microscopically, thermal energy is the kinetic energy associated with the random motion of atoms and molecules. Temperature is a ...

Quantifying Work

As a system undergoes a change, its internal energy can change, and energy can be transferred from the system to the surroundings, or from the ...

Enthalpy

Chemists ordinarily use a property known as enthalpy (H) to describe the thermodynamics of chemical and physical processes. Enthalpy is defined as the sum ...

Thermochemical Equations

For a chemical reaction (the system) carried out at constant pressure &ndash; with the only work done caused by expansion or contraction &ndash; the ...

Constant Pressure Calorimetry

Calorimetry is a technique used to measure the amount of heat involved in a chemical or physical process or to measure the heat transferred to or from a ...

Use mathematics and computational thinking to execute simple calorimetric calculations based on the Law of Conservation of Energy.

Understand the relationship among pressure, temperature, volume, and phase.

How Energy Changes in Chemical Reactions

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