Chapter 8
Reactions of Alkenes
Regioselectivity of Electrophilic Additions-Peroxide Effect
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In the presence of organic peroxides, the addition of hydrogen bromide to an alkene yields the isomer that is not predicted by Markovnikov’s…
Free-Radical Chain Reaction and Polymerization of Alkenes
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The conversion of alkenes to macromolecules called polymers is a reaction of high commercial importance. The structure of the polymer is defined by a…
Halogenation of Alkenes
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Halogenation is the addition of chlorine or bromine across the double bond in an alkene to yield a vicinal dihalide. The reaction occurs in the…
Formation of Halohydrin from Alkenes
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An alkene, such as propene, reacts with bromine in the presence of water to yield a halohydrin. Halohydrins contain a halogen and a hydroxyl group…
Acid-Catalyzed Hydration of Alkenes
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Alkenes react with water in the presence of an acid to form an alcohol. In the absence of acid, hydration of alkenes does not occur at a significant…
Regioselectivity and Stereochemistry of Acid-Catalyzed Hydration
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The rate of acid-catalyzed hydration of alkenes depends on the alkene's structure, as the presence of alkyl substituents at the double bond can…
Oxymercuration-Reduction of Alkenes
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Oxymercuration–reduction of alkenes is one of the major reactions converting alkenes to alcohols. It involves the hydration of alkenes with…
Hydroboration-Oxidation of Alkenes
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In addition to the oxymercuration–demercuration method, which converts the alkenes to alcohols with Markovnikov orientation, a complementary…
Regioselectivity and Stereochemistry of Hydroboration
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A significant aspect of hydroboration–oxidation is the regio- and stereochemical outcome of the reaction.
Hydroboration proceeds in a concerted…
Oxidation of Alkenes: Syn Dihydroxylation with Osmium Tetraoxide
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Alkenes are converted to 1,2-diols or glycols through a process called dihydroxylation. It involves the addition of two hydroxyl groups across the…
Oxidation of Alkenes: Syn Dihydroxylation with Potassium Permanganate
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Alkenes can be dihydroxylated using potassium permanganate. The method encompasses the reaction of an alkene with a cold, dilute solution of…
Oxidation of Alkenes: Anti Dihydroxylation with Peroxy Acids
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Diols are compounds with two hydroxyl groups. In addition to syn dihydroxylation, diols can also be synthesized through the process of anti…
Oxidative Cleavage of Alkenes: Ozonolysis
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In ozonolysis, ozone is used to cleave a carbon–carbon double bond to form aldehydes and ketones, or carboxylic acids, depending on the…
Reduction of Alkenes: Catalytic Hydrogenation
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Alkenes undergo reduction by the addition of molecular hydrogen to give alkanes. Because the process generally occurs in the presence of a…
Reduction of Alkenes: Asymmetric Catalytic Hydrogenation
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Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of…
A standardized technique for atom transfer radical polymerization of vinyl monomers using perylene as a visible-light photocatalyst is presented. The…
Elemental sulfur (S8) is a byproduct of the petroleum industry with millions of tons produced annually. Such abundant production and limited…