Ternary System

A ternary system in chemistry is a system containing three chemically distinct components whose composition and phase behavior are studied together. It matters because interactions among the components can produce mixtures with phase boundaries and properties that differ from those of binary systems. In a ternary phase diagram, each vertex represents a pure component, while positions within the triangle indicate composition; changes in temperature or pressure can shift equilibrium, causing liquid-liquid, solid-liquid, or multiphase separation described by tie lines and phase regions. These diagrams guide the formulation and separation of alloys, solvents, pharmaceuticals, and other multicomponent materials while helping researchers predict stability, crystallization, and processing outcomes.

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Education

JoVE Core - Physical Chemistry

Phase Diagrams of Ternary Systems

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2026

Consider a ternary system, which is composed of three components: water (W), ethanoic acid (E), and trichloromethane (T). Here, Ethanoic acid (E) is fully miscible with both water (W) and trichloromethane (T), meaning it can mix entirely with either of them. However, water and trichloromethane have partial miscibility, meaning they can only mix to a certain extent, beyond which two separate phases will form.The phase diagram of a ternary system is represented as an equilateral triangle, where...

Research

JoVE Journal - Chemistry
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Preparation of Binary and Ternary Deep Eutectic Systems

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Cited by 19 •

2019

This protocol aims to standardize the preparation of deep eutectic systems throughout the scientific community so that these systems can be reproduced.

Thermochemical Studies of Ni(II) and Zn(II) Ternary Complexes Using Ion Mobility-Mass Spectrometry

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Cited by 5 •

2022

This article describes an experimental protocol using electrospray-ion mobility-mass spectrometry, semi-empirical quantum calculations, and energy-resolved threshold collision-induced dissociation to measure the relative thermochemistry of the dissociation of related ternary metal complexes.

Solution-Processed "Silver-Bismuth-Iodine" Ternary Thin Films for Lead-Free Photovoltaic Absorbers

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Cited by 3 •

2018

Herein, we present detailed protocols for solution-processed silver-bismuth-iodine (Ag-Bi-I) ternary semiconductor thin films fabricated on TiO2-coated transparent electrodes and their potential application as air-stable and lead-free optoelectronic devices.

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates

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Cited by 1 •

2016

This article describes construction of a series of hydrogen-bonding supramolecular clusters in crystals using primary ammonium triphenylacetates, which are recrystallized from non-polar solvents. This selective construction of the supramolecular clusters leads to effective systematical symmetric studies about a correlation between the supramolecular clusters and their components.

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