Electric Dipole

An electric dipole is a pair of equal and opposite electric charges separated by a finite distance, forming a fundamental model for charge distributions in physics. Its strength and orientation are described by the dipole moment, a vector directed from the negative charge to the positive charge; in an external electric field, the dipole can experience a force, torque, and changes in potential energy. Electric dipoles help explain polarization in dielectric materials, molecular behavior, electric fields, and interactions between charged objects. Studying their fields and energy provides a foundation for electromagnetism, spectroscopy, materials science, and the analysis of more complex charge configurations.

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JoVE Core - Physics

Electric Dipoles and Dipole Moment

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2026

Consider two charges of equal magnitude but opposite signs. If they cannot be separated by an external electric field, the system is called a permanent dipole. For example, the water molecule is a dipole, making it a good solvent. Theoretically, studying electric dipoles leads to understanding why the resultant electric forces around us are weak. Since electric forces are strong, remnant net charges are rare. Hence, the interaction between dipoles helps us understand electrical interactions in...

Induced Electric Dipoles

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2026

A permanent electric dipole orients itself along an external electric field. This rotation can be quantified by defining the potential energy because the external torque does work in rotating it. Then, the potential energy is minimum at the parallel configuration and maximum at the antiparallel configuration. While the former is a stable equilibrium, the latter is an unstable equilibrium. Since the absolute value of potential energy holds no physical meaning, its zero value can be chosen as per...

Bond Polarity, Dipole Moment, and Percent Ionic Character

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2020

Bond Polarity The absolute value of the difference in electronegativity (ΔEN) of two bonded atoms provides a rough measure of the polarity to be expected in the bond and, thus, the bond type. When the difference is very small or zero, the bond is covalent and nonpolar. When it is large, the bond is polar covalent or ionic. The absolute values of the electronegativity differences between the atoms in the bonds H–H, H–Cl, and Na–Cl are 0 (nonpolar), 0.9 (polar covalent), and 2.1 (ionic),...

IR Spectrum Peak Intensity: Dipole Moment

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2024

The dipole moment of a bond is the product of the partial charge on either atom and the distance between them. Dipole moments influence the efficiency of IR absorption and the peak intensity. When a bond with a dipole moment is placed in an electric field, the direction of the field determines if the bond is compressed or stretched. Electromagnetic radiation consists of an electric field component that rapidly reverses direction. It follows that polar bonds are alternately stretched and...

Molecular Geometry and Dipole Moments

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2023

The VSEPR theory can be used to determine the electron pair geometries and molecular structures as follows: Write the Lewis structure of the molecule or polyatomic ion. Count the number of electron groups (lone pairs and bonds) around the central atom. A single, double, or triple bond counts as one region of electron density. Identify the electron-pair geometry based on the number of electron groups. Use the number of lone pairs to determine the molecular structure. If more than one...

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