synthesis-ligand-free-cds-nanoparticles-within-sulfur-copolymer

Synthesis of Ligand-free CdS Nanoparticles within a Sulfur Copolymer Matrix

Aliphatic ligands are typically used during the synthesis of nanoparticles to help mediate their growth in addition to operating as high-temperature ...

Helmholtz-Zentrum Berlin für Materialien und Energie GmbH

Solution-processable oligoselenophenes functionalized with diketopyrrolopyrrole cores have been synthesized for use as the donor material in bulk heterojunction solar cells. The optical absorption of these materials extends to the edge of the visible spectrum. Power conversion efficiencies of 1.53 ± 0.04% for DPPS and 0.84 ± 0.04% for DPPDS were obtained under simulated 100 mW/cm(2) AM 1.5G irradiation for devices when PC(61)BM was used as an acceptor. DPPS showed hole mobilities of 4 × 10(-5) cm(2)/(V s) and a peak external quantum efficiency (EQE) of 25%, while DPPDS showed hole mobilities of 2 × 10(-5) cm(2)/(V s) and a peak EQE of 19%. To the best of our knowledge, these are the first oligoselenophenes that have been reported in molecular bulk heterojunction solar cells and this study could serve as a springboard for the design and optimization of high-performance selenophene-containing photovoltaics.

Oligoselenophene derivatives functionalized with a diketopyrrolopyrrole core for molecular bulk heterojunction solar cells.

Poly(3-methylthiophene) (P3MT) was synthesized directly from indium tin oxide (ITO) electrodes modified with a phosphonic acid initiator, using Kumada catalyst transfer polymerization (KCTP). This work represents the first time that polymer thickness has been controlled in a surface initiated KCTP reaction, highlighting the utility of KCTP in achieving controlled polymerizations. Polymer film thicknesses were regulated by the variation of the solution monomer concentration and ranged from 30 to 265 nm. Electrochemical oxidative doping of these films was used to manipulate their near surface composition and effective work function. Doped states of the P3MT film are maintained even after the sample is removed from solution and potential control confirming the robustness of the films. Such materials with controllable thicknesses and electronic properties have the potential to be useful as interlayer materials for organic electronic applications.

Surface-initiated synthesis of poly(3-methylthiophene) from indium tin oxide and its electrochemical properties.

A one pot method for organic/colloidal CdSe nanoparticle hybrid material synthesis is presented. Relative to traditional ligand exchange processes, these materials require smaller amounts of the desired capping ligand, shorter syntheses and fewer processing steps, while maintaining nanoparticle morphology.

A one pot organic/CdSe nanoparticle hybrid material synthesis with in situ π-conjugated ligand functionalization.

Increasing global demand for energy, along with dwindling fossil fuel resources and a better understanding of the hidden costs associated with these energy sources, have spurred substantial political, academic, and industrial interest in alternative energy resources. Photovoltaics based on organic semiconductors have emerged as promising low-cost alternatives for electricity generation that relies on sunlight. In this tutorial review we discuss the relevance of these organic photovoltaics beginning with some of the economic drivers for these technologies. We then examine the basic properties of these devices, including operation and materials requirements, in addition to presenting the development of the field from a historical perspective. Potential future directions are also briefly discussed. This tutorial review is intended to be an essential overview of the progress of the field, in addition to aiding in the discussion of the future of OPV technologies.

The future of organic photovoltaics.

Organic coordinating ligands are ubiquitously used to solubilize, stabilize and functionalize colloidal nanoparticles. Aliphatic organic ligands are typically used to control size during the nanoparticle growth period and are used as a high boiling point solvent for solution-based synthesis procedures. However, these aliphatic ligands are typically not well suited for the end use of the nanoparticles, so additional ligand exchange or ligand stripping procedures must be implemented after the nanoparticle synthesis. Herein we present a ligand-free CdS nanoparticle synthesis procedure using a unique sulfur copolymer. The sulfur copolymer is derived from elemental sulfur, which is a cheap and abundant material. This copolymer is used as a sulfur source and high boiling point solvent, which produces stabilized metal-sulfide nanoparticles that are suspended within a sulfur copolymer matrix. The copolymer can then be removed, thereby yielding ligand-free metal-sulfide nanoparticles.

Sulfur copolymer for the direct synthesis of ligand-free CdS nanoparticles.

Correction for 'The future of organic photovoltaics' by Katherine A. Mazzio et al., Chem. Soc. Rev., 2015, 44, 78-90.

Article	Year
Oligoselenophene derivatives functionalized with a diketopyrrolopyrrole core for molecular bulk heterojunction solar cells. ACS applied materials & interfaces\| PubMed ID: 21218797	2011
Surface-initiated synthesis of poly(3-methylthiophene) from indium tin oxide and its electrochemical properties. Langmuir : the ACS journal of surfaces and colloids\| PubMed ID: 22149001	2012
A one pot organic/CdSe nanoparticle hybrid material synthesis with in situ π-conjugated ligand functionalization. Chemical communications (Cambridge, England)\| PubMed ID: 23295326	2013
The future of organic photovoltaics. Chemical Society reviews\| PubMed ID: 25198769	2015
Sulfur copolymer for the direct synthesis of ligand-free CdS nanoparticles. Chemical communications (Cambridge, England)\| PubMed ID: 26077505	2015
Correction: The future of organic photovoltaics. Chemical Society reviews\| PubMed ID: 26095004	2015

Katherine A. Mazzio

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