preparation-of-biopolymer-aerogels-using-green-solvents

Preparation of Biopolymer Aerogels Using Green Solvents

Although the first reports on aerogels made by Kistler1 in the 1930s dealt with aerogels from both inorganic oxides (silica and others) and biopolymers ...

Hamburg University of Technology

A facile deposition method of 3D photonic crystals made of yttrium-stabilized zirconia (YSZ) was developed. YSZ nanoparticles with primary particle size below 10 nm and cubic crystalline phase were synthesized by hydrothermal treatment of solutions of zirconyl nitrate, yttrium nitrate and acetylacetone. Before coassembly with polystyrene (PS) microspheres, a dispersant Dolapix CE64 was added to the dialyzed sol of YSZ nanoparticles to render their surface negatively charged. Vertical convective coassembly resulted in 3D ordered YSZ/PS hybrid films, which were inverted at 500 °C in air to produce inverse opals. The linear shrinkage of the coatings was in the range 15-20%, below previously reported values for YSZ. The obtained coatings demonstrated pronounced photonic properties and retained their ordered structure after annealing at 1000 °C for 2 h. Increasing the filling fraction of crystalline nanoparticles in the templates should enable production of fully functional 3D photonic crystals for applications in high-temperature photonics.

Raman Subrahmanyam

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