isolation-mandibular-gland-reservoir-contents-from-bornean-exploding

Isolation of Mandibular Gland Reservoir Contents from Bornean 'Exploding Ants' (<em>Formicidae</em>) for Volatilome Analysis by GC-MS and MetaboliteDetector

The aim of this manuscript is to present a protocol describing the metabolomic analysis of Bornean &#39;exploding ants&#39; belonging to the Colobopsis ...

Universiti Brunei Darussalam, Brunei

This research is on the evaluation of biosorption capability of the core of Artocarpus odoratissimus (Tarap), grown in Brunei Darussalam, towards Cd(II) and Cu(II) ions present in synthetic solutions, and to characterize the surface of Tarap particles.

Biosorption of cadmium(II) and copper(II) ions from aqueous solution by core of Artocarpus odoratissimus.

Breadnut skin, in both its unmodified (KS) and base-modified (BM-KS) forms, was investigated for its potential use as a low-cost adsorbent for the removal of toxic dye, malachite green (MG). Characterization of the adsorbents was carried out using scanning electron microscope, X-ray fluorescence and Fourier transform infra-red spectroscopy. Batch adsorption experiments, carried out under optimized conditions, for the adsorption of MG were fitted using five isotherm models (Langmuir, Freundlich, Dubinin-Radushkevich, Temkin and Sips) and six error functions to determine the best-fit model. The adsorption capacity was greatly enhanced when breadnut skin was chemically modified with NaOH, leading to an adsorption capacity of 353.0 mg g(-1), that was far superior to most reported adsorbents for the removal of MG. Thermodynamics studies indicated that the adsorption of MG was spontaneous on KS and BM-KS, and the reactions were endothermic and exothermic, respectively. Kinetics studies showed that both followed the pseudo-second order. Regeneration experiments on BM-KS indicated that its adsorption capacity was still maintained at>90% even after five cycles. It can be concluded that NaOH-modified breadfruit skin has great potential to be utilized in real-life application as a low-cost adsorbent for the removal of MG in wastewater treatment. 

Enhancing adsorption capacity of toxic malachite green dye through chemically modified breadnut peel: equilibrium, thermodynamics, kinetics and regeneration studies.

Cempedak durian peel (CDP) was used to remove Brilliant Green (BG) dye from aqueous solution. The adsorption of BG onto CDP was studied as functions of contact time, pH, temperature, ionic strength and initial concentration. In order to understand the adsorption process and its mechanisms, adsorption isotherm and kinetics models were used. The experiments were done under optimized 2-h contact time and ambient pH. Adsorption study showed that the Langmuir model best fitted with experimental data, and the maximum adsorption capacity was determined as 0.203 mmol g(-1) (97.995 mg g(-1)). Adsorption kinetics followed the pseudo 2nd order model, and intraparticle diffusion is involved but not as the rate-limiting step while Boyd model suggests that film diffusion might be in control of the adsorption process. Fourier transform infrared (FTIR) analysis showed that OH, C=O, C=C and NH functional groups might be involved in the adsorption of BG onto CDP. Thermodynamic study suggested that the adsorption of BG onto CDP is endothermic with ΔH (o) value of 12 kJ mol(-1) and adsorption is feasible. Regeneration of CDP's ability to remove BG was also studied using three different washing solutions. NaOH (0.1 M) was not only sufficient to be used to regenerate CDP's ability to remove BG but also improved its adsorption capability. 

Cempedak durian as a potential biosorbent for the removal of Brilliant Green dye from aqueous solution: equilibrium, thermodynamics and kinetics studies.

This study investigated the potential of untreated Azolla pinnata (AP) to remove toxic rhodamine B (RB) dye. The effects of adsorbent dosage, pH, ionic strength, contact time, and concentration were studied. Experiments involving the effects of pH and ionic strength indicated that hydrophobic-hydrophobic interactions might be the dominant force of attraction for the RB-AP adsorption system. The kinetics modelling of the kinetics experiment showed that pseudo-second-order best represented the adsorption process. The Weber-Morris intraparticle diffusion model showed that intraparticle diffusion is not the rate-limiting step, while the Boyd model suggested that film diffusion might be rate-limiting. The adsorption isotherm model, Langmuir, best represented the adsorption process, and the maximum adsorption capacity was predicted to be 72.2 and 199.7 mg g(-1) at 25 and 65 °C, respectively. Thermodynamics study indicates spontaneity, endothermic and physisorption-dominant adsorption process. The adsorbents were regenerated to satisfactory level with distilled water, HNO3 and NaOH. Pre-treatment of adsorbent with oxalic acid, citric acid, NaOH, HCl and phosphoric acid was investigated but the adsorption capacity was less than the untreated AP.

Separation of toxic rhodamine B from aqueous solution using an efficient low-cost material, Azolla pinnata, by adsorption method.

Co-dominant effect of selected natural dye sensitizers in DSSC performance.

This study investigated the potential of Azolla pinnata (AP) in the removal of toxic methyl violet 2B (MV) dye wastewater using the phytoextraction approach with the inclusion of an Artificial Neural Network (ANN) modelling. Parameters examined included the effects of dye concentration, pH and plant dosage. The highest removal efficiency was 93% which was achieved at a plant dosage of 0.8 g (dye volume = 200 mL, initial pH = 6.0, initial dye concentration = 10 mg L). A significant decrease in relative frond number (RFN), a growth rate estimator, observed at a dye concentration of 20 mg L MV indicated some toxicity, which coincided with the plant pigments studies where the chlorophyll a content was lower than the control. There were little differences in the plant pigment contents between the control and those in the presence of dye (5 to 15 mg L) indicating the tolerance of AP to MV at lower concentrations. A three-layer ANN model was optimized (6 neurons in the hidden layer) and successfully predicted the phytoextraction of MV (R = 0.9989, RMSE = 0.0098). In conclusion, AP proved to be a suitable plant that could be used for the phytoextraction of MV while the ANN modelling has shown to be a reliable method for the modelling of phytoextraction of MV using AP.

Article	Year
Biosorption of cadmium(II) and copper(II) ions from aqueous solution by core of Artocarpus odoratissimus. Environmental science and pollution research international\| PubMed ID: 22392692	2012
Enhancing adsorption capacity of toxic malachite green dye through chemically modified breadnut peel: equilibrium, thermodynamics, kinetics and regeneration studies. Environmental technology\| PubMed ID: 25409587	2015
Cempedak durian as a potential biosorbent for the removal of Brilliant Green dye from aqueous solution: equilibrium, thermodynamics and kinetics studies. Environmental monitoring and assessment\| PubMed ID: 26231977	2015
Separation of toxic rhodamine B from aqueous solution using an efficient low-cost material, Azolla pinnata, by adsorption method. Environmental monitoring and assessment\| PubMed ID: 26797814	2016
Co-dominant effect of selected natural dye sensitizers in DSSC performance. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy\| PubMed ID: 27236204	2016
Phytoextraction potential of water fern (Azolla pinnata) in the removal of a hazardous dye, methyl violet 2B: Artificial neural network modelling. International journal of phytoremediation\| PubMed ID: 28862490	2018

Linda B.L. Lim

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