fabrication-and-design-of-wood-based-high-performance-composites

Fabrication and Design of Wood-Based High-Performance Composites

Delignified densified wood is a new promising and sustainable material that possesses the potential to replace synthetic materials, such as glass fiber ...

ETH Zurich

EMPA

Microcapsules for controlled chemical release and uptake are important in many industrial applications but are often difficult to produce with the desired combination of high mechanical strength and high shell permeability. Using water-oil-water double emulsions made in microfluidic devices as templates, we developed a processing route to obtain mechanically robust microcapsules exhibiting a porous shell structure with controlled permeability. The porous shell consists of a network of interconnected polymer particles that are formed upon phase separation within the oil phase of the double emulsion. Porosity is generated by an inert diluent incorporated in the oil phase. The use of undecanol and butanol as inert diluents allows for the preparation of microcapsules covering a wide range of shell-porosity and force-at-break values. We found that the amount and chemical nature of the diluent influence the shell porous structure by changing the mechanism of phase separation that occurs during polymerization. In a proof-of-concept experiment, we demonstrate that the mechanically robust microcapsules prepared through this simple approach can be utilized for the on-demand release of small molecules using a pH change as exemplary chemical trigger.

Strong Microcapsules with Permeable Porous Shells Made through Phase Separation in Double Emulsions.

Today's materials research aims at excellent mechanical performance in combination with advanced functionality. In this regard, great progress has been made in tailoring the materials by assembly processes in bottom-up approaches. In the field of wood-derived materials, nanocellulose research has gained increasing attention, and materials with advanced properties were developed. However, there are still unresolved issues concerning upscaling for large-scale applications. Alternatively, the sophisticated hierarchical scaffold of wood can be utilized in a top-down approach to upscale functionalization, and one can profit at the same time from its renewable nature, CO storing capacity, light weight, and good mechanical performance. Nevertheless, for bulk wood materials, a wider multipurpose industrial use is so far impeded by concerns regarding durability, natural heterogeneity as well as limitations in terms of functionalization, processing, and shaping. Here, we present a novel cellulose bulk material concept based on delignification and densification of wood resulting in a high-performance material. A delignification process using hydrogen peroxide and acetic acid was optimized to delignify the entire bulk wooden blocks and to retain the highly beneficial structural directionality of wood. In a subsequent step, these cellulosic blocks were densified in a process combining compression and lateral shear to gain a very compact cellulosic material with entangled fibers while retaining unidirectional fiber orientation. The cellulose bulk materials obtained by different densification protocols were structurally, chemically, and mechanically characterized revealing superior tensile properties compared to native wood. Furthermore, after delignification, the cellulose bulk material can be easily formed into different shapes, and the delignification facilitates functionalization of the bioscaffold.

Delignified and Densified Cellulose Bulk Materials with Excellent Tensile Properties for Sustainable Engineering.

Elegant design principles in biological materials such as stiffness gradients or sophisticated interfaces provide ingenious solutions for an efficient improvement of their mechanical properties. When materials such as wood are directly used in high-performance applications, it is not possible to entirely profit from these optimizations because stiffness alterations and fiber alignment of the natural material are not designed for the desired application. In this work, wood is turned into a versatile engineering material by incorporating mechanical gradients and by locally adapting the fiber alignment, using a shaping mechanism enabled by reversible interlocks between wood cells. Delignification of the renewable resource wood, a subsequent topographic stacking of the cellulosic scaffolds, and a final densification allow fabrication of desired 3D shapes with tunable fiber architecture. Additionally, prior functionalization of the cellulose scaffolds allows for obtaining tunable functionality combined with mechanical gradients. Locally controllable elastic moduli between 5 and 35 GPa are obtained, inspired by the ability of trees to tailor their macro- and micro-structure. The versatility of this approach has significant relevance in the emerging field of high-performance materials from renewable resources.

Tunable Wood by Reversible Interlocking and Bioinspired Mechanical Gradients.

Wood represents a highly suitable biobased scaffold for the development of mechanically robust and functional materials. Its functionalizability can be enhanced by means of delignification, resulting in an increase in porosity due to partial or complete removal of lignin and hemicellulose constituents. In this work, the impact of partial and complete delignification on the mesoporous structure is investigated via water vapor sorption isotherms and deuterium exchange. Pore size distributions of wood samples with five different delignification levels were compared to native wood. The derived pore size distributions at the water swollen state reveal an increase in porosity with decreasing lignin content. However, after complete lignin removal, drying causes a nonreversible collapse of the cell wall, which results in reduced porosity.

Article	Year
Strong Microcapsules with Permeable Porous Shells Made through Phase Separation in Double Emulsions. Langmuir : the ACS journal of surfaces and colloids\| PubMed ID: 28195737	2017
Delignified and Densified Cellulose Bulk Materials with Excellent Tensile Properties for Sustainable Engineering. ACS applied materials & interfaces\| PubMed ID: 29373784	2018
Tunable Wood by Reversible Interlocking and Bioinspired Mechanical Gradients. Advanced science (Weinheim, Baden-Wurttemberg, Germany)\| PubMed ID: 31131194	2019
Mesoporosity of Delignified Wood Investigated by Water Vapor Sorption. ACS omega\| PubMed ID: 31460361	2019

Marion Frey

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