scalable-syntheses-graphene-oxide-reduced-graphene-oxide-using

Scalable Syntheses of Graphene Oxide and Reduced Graphene Oxide using Cascade Design Oxidation and Highly Basic Reduction Reactions

This present work describes the scalable synthetic methods of oxidation and reduction reactions for producing graphene oxide and reduced graphene oxide ...

VNUHCM University of Science

Vietnam National University, Ho Chi Minh City (VNUHCM)

In this investigation, cobalt ferrite nanoparticles (CFO NPs) were synthesized using a hydrothermal method. Then, silver nanoparticles (Ag NPs) were decorated on CFO NPs to form Ag/CFO NPs using jasmine extract as a reducing agent of Ag ions. The properties of Ag/CFO NPs were characterized by X-ray powder diffraction, field-emission scanning electron microscopy, energy-dispersive X-ray spectroscopy, Fourier-transform infrared spectroscopy, vibrating sample magnetometry, and catalytic tests in non-radiation conditions. The catalytic results indicated that the Ag/CFO NPs could activate peroxymonosulfate to generate sulfate radicals for the decomposition of different dyes such as methylene blue, methyl orange, and rhodamine B. For the Ag/CFO sample, Ag NPs validated the roles in dye adsorption, reduction of 4-nitrophenol, and improvement of antibacterial behavior. The growth inhibition activity of Ag/CFO NPs was observed against  (18.18 ± 2.48 mm) and  (10.14 ± 0.72 mm). Furthermore, Ag/CFO NPs displayed good reusability after three consecutive runs. Therefore, Ag/CFO material is shown to be a potential multifunctional catalyst in wastewater treatment.

Silver decorated on cobalt ferrite nanoparticles as a reusable multifunctional catalyst for water treatment applications in non-radiation conditions.

An improvement to Hummers' method involving a cascade-design graphite oxidation reaction is reported to optimize safety and efficiency in the production of graphite oxide (GrO) and graphene oxide (GO). Chemical reduction using highly alkaline ammonia solution is a novel approach to synthesizing reduced graphene oxide (RGO). In this original research, we revisit the oxidation and reduction reactions, providing significant findings regarding the synthetic pathway to obtain a bioinspired water-intercalated hydrogel of RGO nanosheets. Influential factors in the graphite oxidation reaction, typically the exothermic reaction temperature and hydrogen peroxide effect, are described. Furthermore, the chemical reaction of GO reduction using highly alkaline ammonia solution (pH 14) was investigated to produce hydrated RGO nanosheets assembled in a hydrogel structure (97% water). Three-dimensional assembly and water intercalation are key to preserve the non-stacking state of RGO nanosheets. Therefore, ultrasound transmission to aqueous channels in the macroscopic RGO hydrogel vibrated and dispersed the RGO nanosheets in water. Analytical results revealed the single-layer nanostructures, functional groups, optical band gaps, optimized C/O ratios, particle sizes and zeta potentials of GO and RGO nanosheets. The reversible self-assembly of RGO hydrogels is essential for many applications, such as RGO coatings and polymer/RGO nanocomposites. In a water purification application, the RGO hydrogel was dispersed in aqueous solution by simple agitation and showed a high capacity for organic dye adsorption. After the adsorption, the RGO/dye particles were easily removed by filtration through ordinary cellulose paper. The process of adsorption and filtration is effective and inexpensive for practical environmental remediation. In summary, a bioinspired structure of RGO hydrogel is conceptualized for prospective nanotechnology.

Article	Year
Silver decorated on cobalt ferrite nanoparticles as a reusable multifunctional catalyst for water treatment applications in non-radiation conditions. RSC advances\| PubMed ID: 37593663	2023
Revisiting oxidation and reduction reactions for synthesizing a three-dimensional hydrogel of reduced graphene oxide. RSC advances\| PubMed ID: 39346523	2024

Van Hieu Le

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