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Effektiv syntese af alle-Carbon kvaternære Centre via konjugat tilføjelsen af Funktionaliserede Monoorganozinc bromider
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Effektiv syntese af alle-Carbon kvaternære Centre via konjugat tilføjelsen af Funktionaliserede Monoorganozinc bromider

Article DOI: 10.3791/59775-v • 07:50 min • May 26th, 2019
May 26th, 2019 •
1, 2, 2
1Warren and Katharine Schlinger Laboratory for Chemistry and Chemical Engineering, California Institute of Technology, 2Department of Chemistry, Bucknell University

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En enkel og praktisk protokol for effektiv konjugat tilsætning af funktionaliserede monoorganozinc bromider til cykliske α, β-umættede carbonyler til at fremlægge alle-Carbon kvaternære Centre blev udviklet.

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Kemi organozinc reagens kobber konjugat addition kvaternære Center katalyse organometallic stereoselektive
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