Name: gas work in a piston cylinder
Uploaded: 2023-04-30T12:31:11.000Z
Duration: 1 min 17 s
Channel: JoVE

K12 Standards

new-jersey-student-learning-standards-for-science

New Jersey Student Learning Standards for Science

High School

Physical Science

Energy

HS-PS3-4

Work Done During Volume Change

Stellen Sie sich einen aufgeblasenen Fußball mit einem Volumen von V vor. Der Druck, der auf den Ball wirkt, ist der atmosphärische Druck.
Angenommen, der Ball fällt von der Klippe und wird durchstochen, dann wird die Luft im Inneren des Balls freigesetzt. Unter der Annahme einer gleichmäßigen Deflation verkleinere sich ihr Radius um einen Abstand von dr.
Die Größe der Kraft, die auf die Kugel wirkt, hängt vom atmosphärischen Druck und der Oberfläche der Kugel ab.
Daher entspricht die Arbeit, die die Umgebung an der Kugel leistet, dem negativen Produkt aus dem atmosphärischen Druck, der Oberfläche der Kugel und der Änderung ihres Radius.
Das Produkt aus Oberfläche und Dr ist jedoch die Änderung des Volumens der Kugel.
Daher kann während einer endlichen Volumenänderung von V1 auf V2 die geleistete Arbeit als Integral aus dem Produkt aus Druck und Volumenänderung ausgedrückt werden.
Hier zeigt das negative Vorzeichen an, dass die Arbeit an der Anlage von der Umgebung ausgeführt wird. Umgekehrt wird die vom System geleistete Arbeit als positiv bewertet.

<ol>
	<li>OpenStax. (2019). Universitätsphysik Vol. 1. [Webversion]. Pp 112 Abgerufen von <a href="https://openstax.org/books/university-physics-volume-2/pages/3-2-work-heat-and-internal-energy">https://openstax.org/books/university-physics-volume-2/pages/3-2-work-heat-and-internal-energy</a></li>
</ol>

arbeit bei volumenänderung

In der Mechanik wird Arbeit an einem Objekt verrichtet, wenn die auf es wirkende Kraft das Objekt verschiebt. In der Thermodynamik kann die an einem System verrichtete Arbeit geschätzt werden, wenn sich das Volumen des Systems während eines thermodynamischen Prozesses ändert.

Betrachten Sie ein Gas, das in einem mit einem beweglichen Kolben ausgestatteten Zylinder eingeschlossen ist. Wenn das Gas von Volumen V1 auf Volumen V2 expandiert, wirkt es eine Kraft auf den Kolben aus, sodass der Kolben sich um eine Strecke dr bewegt.

Die von dem Gas auf den Kolben verrichtete Arbeit kann ausgedrückt werden als

<img alt="Equation1" src="/files/ftp_upload/13675/13675_Equation_PT_1.svg" style="text-align: center; height: 10px;" />

Wenn p der Druck ist, der auf die Fläche A des Kolbens wirkt, dann ist die auf den Kolben ausgeübte Kraft

<img alt="Equation2" src="/files/ftp_upload/13675/13675_Equation_PT_2.svg" style="text-align: center; height: 12px;" />

Folglich kann die verrichtete Arbeit ausgedrückt werden als

<img alt="Equation3" src="/files/ftp_upload/13675/13675_Equation_PT_3.svg" style="text-align: center; height: 12px;" />

Die Änderung des Gasvolumens dV entspricht Adr. Daher wird die von dem Gas auf den Kolben verrichtete Arbeit, wenn es von Volumen V1 auf Volumen V2 expandiert, ausgedrückt als

<img alt="Equation4" src="/files/ftp_upload/13675/13675_Equation_PT_4.svg" style="text-align: center; height: 45px;" />

Hierbei ist das Integral nur sinnvoll für einen quasi-statischen Prozess, d.h. einen Prozess, der in unendlich kleinen Schritten stattfindet und das System im thermischen Gleichgewicht hält.

Wenn der Kolben das Gas komprimiert, wird Arbeit am Gas verrichtet und wird daher konventionell als negativ betrachtet.

Arbeit bei Volumenänderung

In der Mechanik wird an einem Objekt gearbeitet, wenn die auf es wirkende Kraft das Objekt verdrängt. In der Thermodynamik kann die Arbeit an einem System abgeschätzt werden, wenn ...

Education

Lehre

JoVE Core

Physics

Physik

Unit 1

Einheit 1

The First Law of Thermodynamics

Der erste Hauptsatz der Thermodynamik

KEY TERMS AND CONCEPTS

KERNBEGRIFFE UND KONZEPTE

gas work in a piston cylinder

Gas work in a piston cylinder describes how pressure and volume change are related in thermodynamics. In mechanics, work happens when a force moves an object. In thermodynamics, work done on a system can be estimated when the system changes volume during a process.

A gas can be trapped in a cylinder with a movable piston at one end. When the gas expands from volume V1 to volume V2, it pushes on the piston and moves it by a small distance dr. If the pressure on the piston face is p and the piston area is A, the force on the piston is based on that pressure.

The work done by the gas can then be written in terms of pressure, area, and piston motion. Because the change in volume dV equals A dr, the work can also be expressed as an integral from V1 to V2. This form is meaningful only for a quasi-static process, which means the change happens in very small steps while the system stays in thermal equilibrium.

If the piston compresses the gas, the direction of work reverses. In that case, work is done on the gas, and it is conventionally treated as negative.

Gas Work in a Piston Cylinder

thermodynamic systems

Open, Closed, and Isolated Systems

A thermodynamic system is the part of the world that scientists study for its heat and energy behavior. It sits inside a surrounding environment, or surroundings. The system and the surroundings can exchange heat and do work across the boundary that separates them. The immediate surroundings affect the system most strongly because they interact with it directly. A kettle of boiling tea shows how this works in everyday life. The tea and the kettle together form the system. If the lid is open,...

work done during volume change

Gas work in a piston cylinder describes how pressure and volume change are related in thermodynamics. In mechanics, work happens when a force moves an object. In thermodynamics, work done on a system can be estimated when the system changes volume during a process. A gas can be trapped in a cylinder with a movable piston at one end. When the gas expands from volume V1 to volume V2, it pushes on the piston and moves it by a small distance dr. If the pressure on the piston face is p and the...

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Path Dependence in Gas Work

Work done by an ideal gas can depend on the path it takes between two thermodynamic states. The transcript compares two routes from state A to state C for the same gas. In both cases, the gas expands from volume V1 to volume V2, but the work is not the same. Along path AC, the gas stays at constant temperature T. It expands from V1 to V2. The work done by the gas is found from the pressure-volume relation for an ideal gas. After substituting pressure as nRT/V and integrating, the work for this...

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internal energy

How Internal Energy Changes in Gas Systems

Internal energy is the energy stored inside a thermodynamic system. It is the sum of the kinetic and potential energies of the molecules or other particles in the system. Molecular kinetic energy includes translational motion, rotation, and vibration. Molecular potential energy comes from interactions between molecules. A system’s location and overall motion do not affect its internal energy. For an ideal monatomic gas, each particle is a single atom. That means there is no rotational or...

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Heat, work, and internal energy are linked by the first law of thermodynamics. This law is a generalized form of energy conservation. It explains how energy changes when heat is added to or removed from a system, and when the system does work or has work done on it. The change in internal energy equals the heat transferred into the system minus the work done by the system. Added heat increases internal energy. For that reason, heat is taken as positive when it enters the system and negative...

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First Law of Thermodynamics: Solving Problems

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Net Work in a Cyclic Thermodynamic Process

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isothermal processes

Isothermal Expansion and Heat Transfer

An isothermal process is a thermodynamic process that happens at constant temperature. During the process, heat slowly flows into the system or out of the system so thermal equilibrium is maintained. Phase changes are common examples of isothermal processes. Water can evaporate into steam at a constant temperature, and water can also freeze into ice at a constant temperature. An ideal gas can also undergo isothermal expansion or compression. Here, an ideal gas in an isolated cylinder expands...

isochoric and isobaric processes

Constant Volume and Pressure in Thermodynamics

Thermodynamic processes can happen at constant volume or at constant pressure. An isochoric process is a constant-volume process. In this case, the volume does not change, so the work done by the system is zero. The first law of thermodynamics still applies, so any heat added or removed changes the internal energy of the system only. A simple example is heating 1000 g of water from 40 degrees celsius to 70 degrees celsius at constant volume. Because the process is isochoric, no work is done by...

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Ideal Gas Heat Capacity at Constant Pressure

Heat capacity describes how much heat a substance absorbs for a given change in temperature. It is also called thermal capacity, and its SI unit is J/K. Specific heat capacity is the heat needed to raise the temperature of 1 kg of a substance by 1 K, and its SI unit is J/kg·K. The video also explains molar heat capacity. This is the amount of heat added or removed to change the temperature of 1 mole of a substance by 1 K. It can be measured at constant volume or constant pressure, and it is...

heat capacities of an ideal gas ii

Ideal Gas Heat Capacity Differences

Ideal gas heat capacities depend on whether the gas is heated at constant volume or constant pressure. At constant volume, the heat absorbed only raises the internal energy of the system. No work is done in this case. At constant pressure, the situation is different. The heat absorbed increases the internal energy and also does work. Molar heat capacity is the heat needed to raise the temperature of 1 mole of gas by 1 unit. Because some of the added heat goes into work, more heat is needed at...

heat capacities of an ideal gas iii

Ideal Gas Heat Capacity and Degrees of Freedom

Ideal gas heat capacity depends on degrees of freedom, which are the independent ways a gas molecule can move, rotate, and vibrate. If d is the number of degrees of freedom, the molar heat capacity at constant volume can be written in terms of d. The molar heat capacity at constant pressure can also be written using the relationship between the two heat capacities. The ratio of molar heat capacity at constant pressure to molar heat capacity at constant volume is called the ratio of heat...

adiabatic processes for an ideal gas

Gas Temperature Changes in Adiabatic Processes

Adiabatic processes change the temperature of an ideal gas without heat transfer. In an adiabatic compression, no heat is added, but work is done on the gas. That work raises the gas temperature. In an adiabatic expansion, the gas does work and its temperature drops. A common example is the compression of a gas-air mixture inside a car engine cylinder. The compression happens so quickly that there is no time for heat to move between the mixture and its surroundings. Even so, the work done on...

pressure and volume in an adiabatic process

pressure-and-volume-in-an-adiabatic-process

Free Expansion: Pressure, Volume, and Temperature

Free expansion shows how pressure, volume, and temperature behave when a gas expands without doing work. It is an adiabatic process, but it is not the same as adiabatic expansion. In free expansion, no work is done and the internal energy does not change. In adiabatic expansion, work is done and the internal energy changes. For an adiabatic process, the pressure-volume relation comes from the adiabatic condition. That relation does not apply to free expansion, even though the expansion is...

work done in an adiabatic process

Adiabatic Compression in an Engine Cylinder

Adiabatic compression in an engine cylinder changes the pressure, temperature, and volume of a gas-air mixture. In this setup, gasoline vapor is injected into the cylinder when the piston is in its expanded position. The mixture starts at 20 °C, 1.00 x 10^5 N/m^2, and 240 cm^3. The mixture is then compressed adiabatically to 40 cm^3. Adiabatic means no heat is exchanged with the surroundings during the process. For this calculation, the compression is treated as quasi-static, even though real...

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Thermodynamic potentials are energy-based state functions used to analyze a thermodynamic system. They help describe how a system changes under different conditions. The four main thermodynamic potentials are internal energy, enthalpy, Helmholtz free energy, and Gibbs free energy. These potentials can be written using two of the variables pressure, volume, temperature, and entropy. In each case, the rate of change of the potential with respect to the other two variables gives useful...

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Using Maxwell's Relations in Thermodynamics

Maxwell's thermodynamic relations help solve problems in thermodynamics. They connect partial differentials for quantities that are hard to measure in the lab with quantities that are easier to measure. This makes them useful for working with temperature, pressure, volume, and entropy. These relations come from thermodynamic potentials and the symmetry of second derivatives. Thermodynamic potentials are exact differentials, so the order of second differentiation does not change the result.

joule-thomson effect

Gas Cooling and Heating in Throttling

Gas cooling and heating in throttling is explained by the Joule-Thomson effect, also called the Joule-Kelvin effect. It describes how a fluid changes temperature when it passes through a valve or porous plug in a thermally insulated system. This type of flow is called a throttling process. In the experiment, a high-pressure gas is forced through a throttle valve or porous plug into a lower-pressure region. The gas expands as it moves into the larger volume. Work is done on the gas as it is...

key terms and concepts

Learn how gas pressure and piston motion create work during expansion or compression, and why quasi-static volume change matters in thermodynamics.

Gas Work in a Piston Cylinder | JoVE K12

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HS-PS3-5

Gas Work in a Piston Cylinder

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