7.4
콘크리트의 전공극량은 겔수 부피, 모세관 기공 및 갇힌 공기를 포함합니다. 겔수(시멘트 수화 생성물 내에 유지됨)와 물리적으로 갇히거나 흡착된 물은 수화 과정에 중요합니다. 완전한 수화를 위해서는 1세제곱 센티미터의 시멘트 생성물에 필요한 공간이 두 배라고 추정됩니다.…
공극의 총 부피에는 겔 물, 모세관 기공 및 갇힌 공기가 차지하는 부피가 포함되며, 각각이 콘크리트 구조물의 전체 다공성에 기여하는 콘크리트 덩어리를 생각해 보십시오.
시멘트 수화의 산물인 겔은 수화물의 광범위한 표면적에 물리적으로 유지되거나 흡착된 고체 물질과 물로 구성됩니다. 이 특정 물의 부피는 젤 워터의 부피입니다.
1입방인치의 수화되지 않은 시멘트는 완전한 수화 시 수화 제품을 위해 약 2입방인치의 공간이 필요한 것으로 추정됩니다.
모세관 기공은 수화 제품이 차지하지 않는 수화 시멘트 페이스트 내의 공간이며, 이러한 기공은 비어 있거나 물로 채워질 수 있습니다.
콘크리트를 혼합하는 과정에서 일부 공기가 시멘트 페이스트 내에 갇히는 경우가 많습니다.
이러한 갇힌 공기 공극은 최대 120mil에 달할 수 있으며, 이는 모세관 공극보다 훨씬 크며 콘크리트의 강도에 부정적인 영향을 미칠 수 있습니다.
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Q1: What are the three main components that make up total voids in concrete?
Total voids in concrete consist of gel water, capillary pores, and entrapped air. Gel water is retained within cement hydration products through physical adsorption onto hydrate surfaces. Capillary pores are unoccupied spaces in the hydrated cement paste, while entrapped air becomes trapped during mixing and can reach up to 120 mils in size, substantially larger than capillary voids.
Q2: How much space is required for cement hydration products compared to unhydrated cement?
During complete hydration, approximately two cubic inches of space are needed for the hydration products of one cubic inch of unhydrated cement. This significant volume expansion occurs because the gel, which is the product of cement hydration, contains both solid substances and water physically retained or adsorbed onto the extensive surface area of the hydrates.
Q3: What is gel water and why is it important in concrete?
Gel water is the volume of water physically retained or adsorbed onto the extensive surface area of cement hydration products. This water is a key component of the gel formed during cement hydration and contributes to the overall porosity of the concrete structure. Understanding gel water volume is essential for assessing the hydration process and concrete performance.
Q4: How do capillary pores differ from entrapped air voids in concrete?
Capillary pores are small, irregularly shaped spaces within hydrated cement paste that range from nanometers to a few micrometers in diameter. Entrapped air voids, typically spherical, are substantially larger, reaching up to 120 mils. The distribution of capillary pores is considered a more precise indicator of hydrated cement paste characteristics than total porosity alone.
Q5: Why do entrapped air voids negatively impact concrete strength?
Entrapped air voids can reach up to 120 mils, making them substantially larger than capillary voids. These large voids reduce the effective load-bearing area and create stress concentration points within the concrete matrix. Understanding and controlling void volume and distribution is essential for optimizing concrete's strength and permeability properties.
Q6: What factors influence the size and distribution of capillary pores?
The size and distribution of capillary pores are largely influenced by the water-to-cement ratio and the degree of hydration. Lower water-to-cement ratios generally produce finer, more densely distributed capillary pores. The distribution of these capillary voids is believed to be a more precise indicator for assessing hydrated cement paste characteristics than total porosity.
Q7: How do voids affect both concrete strength and permeability?
Voids significantly impact concrete by affecting both strength and permeability. Larger entrapped air voids weaken the concrete structure, while capillary pores influence water penetration and durability. To optimize concrete's properties, controlling the volume and distribution of all void types is essential for achieving desired strength and resistance to environmental degradation.