Naphthyl-ethylenediamine

Naphthyl-ethylenediamine, commonly used as N-(1-naphthyl)ethylenediamine, is a chromogenic reagent for detecting nitrite in environmental samples. In the Griess reaction, nitrite reacts with an aromatic amine under acidic conditions to form a diazonium intermediate, which then couples with naphthyl-ethylenediamine to produce a pink or reddish azo dye. The resulting color intensity is measured spectrophotometrically and corresponds to nitrite concentration. This method supports routine analysis of drinking water, wastewater, natural waters, and other samples where nitrogen contamination must be monitored, providing a practical basis for assessing nutrient pollution and treatment performance.

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JoVE Science Education - Environmental Sciences

Determination Of NOx in Automobile Exhaust Using UV-VIS Spectroscopy

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2023

Source: Laboratories of Margaret Workman and Kimberly Frye - Depaul University In the troposphere, ozone is naturally formed when sunlight splits nitrogen dioxide (NO2): NO2 + sunlight → NO + O O + O2 → O3 Ozone (O3) can go on to react with nitric oxide (NO) to form nitrogen dioxide (NO2) and oxygen: NO + O3 → NO2 + O2 This results in no net gain of ozone (O3). However, with the anthropogenic production of ozone forming precursors (NO, NO2, and volatile organic compounds) through the combustion...

Stoichiometry, Product Yield, and Limiting Reactants - Student Protocol

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2020

Source: Smaa Koraym at Johns Hopkins University, MD, USA Synthesis of tris(ethylenediamine)nickel chlorideExpand In this lab, you will combine nickel chloride hexahydrate and ethylenediamine in water to produce tris(ethylenediamine)nickel chloride. When nickel chloride hexahydrate dissolves in water, it rearranges to become the hexaaquanickel cation and two chloride anions. Adding ethylenediamine results in three ethylenediamine molecules exchanging with the six water molecules. This...

Stoichiometry, Product Yield, and Limiting Reactants - Instructor Prep

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2020

Source: Smaa Koraym at Johns Hopkins University, MD, USA Preparation of 25% v/v Ethylenediamine in Deionized WaterExpand Here, we show the laboratory preparation for 10 students working in pairs, with some excess. Please adjust quantities as needed. To set up for this lab experiment, wear the appropriate personal protective equipment, including a lab coat, chemical splash goggles, and gloves. Note: Ethylenediamine is toxic, caustic, flammable, and corrosive. This solution must be...

Coordination Chemistry Complexes

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2023

Source: Laboratory of Dr. Neal Abrams — SUNY College of Environmental Science and Forestry Transition metals are found everywhere from vitamin supplements to electroplating baths. Transition metals also make up the pigments in many paints and compose all minerals. Typically, transition metals are found in the cationic form since they readily oxidize, or lose electrons, and are surrounded by electron donors called ligands. These ligands do not form ionic or covalent bonds with the metal center,...

Stereoisomerism

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2020

Isomerism in Complexes Isomers are different chemical species that have the same chemical formula. Transition metal complexes often exist as geometric isomers, in which the same atoms are connected through the same types of bonds but with differences in their orientation in space. Coordination complexes with two different ligands in the cis and trans positions from a ligand of interest form isomers. For example, the octahedral [Co(NH3)4Cl2]+ ion has two isomers (Figure 1) In the cis...

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