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Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes

Controlled Photoredox Ring-Opening Polymerization of <em>O</em>-Carboxyanhydrides Mediated by Ni/Zn Complexes

JoVE Journal
Chemia

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JoVE Journal Chemia

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes

8,014 Views

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05:48 min

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November 21, 2017

DOI:

10.3791/56654-v

DOI:

10.3791/56654-v

•

05:48 min

November 21, 2017

•

2 Views

Quanyou Feng^1,2, Rong Tong²

¹Center for Molecular Systems and Organic Devices, Institute of Optoelectronic Materials, Key Laboratory for Organic Electronics and Information Displays & Institute of Advanced Materials, Jiangsu National Synergetic Innovation Center for Advanced Materials,Nanjing University of Posts and Telecommunications, ²Department of Chemical Engineering,Virginia Polytechnic Institute and State University

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Podsumowanie

A protocol for the controlled photoredox ring-opening polymerization of O-carboxyanhydrides mediated by Ni/Zn complexes is presented.

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Controlled Photoredox Ring-opening Polymerization O-carboxyanhydrides Ni/zn Complexes Poly(alpha-hydroxy Acids)High Molecular Weight Polyesters Side Chain Functional Groups Anhydrous THF Bipy-nickel(COD)Zinc Bis(hmds)Benzyl Alcohol Iridium Catalyst L1 Monomer Blue LED Light Temperature Control

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