Bond Representation

Bond representation is a set of symbolic methods used to depict how atoms connect and share electrons in molecules, helping chemists communicate molecular structure and reactivity. Depending on the purpose, representations such as Lewis structures, structural formulas, line-angle drawings, and wedge-dash notation use symbols, lines, and spatial conventions to show valence electrons, bond order, connectivity, and three-dimensional arrangement. These models support the analysis of covalent bonding, formal charge, resonance, molecular geometry, and stereochemistry. In chemistry, accurate bond representations help predict reactions, interpret molecular properties, and translate experimental findings into structures used in synthesis, spectroscopy, and computational modeling.

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JoVE Core - Chemistry

Bond Energies and Bond Lengths

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2020

Stable molecules exist because covalent bonds hold the atoms together. The strength of a covalent bond is measured by the energy required to break it, that is, the energy necessary to separate the bonded atoms. Separating any pair of bonded atoms requires energy — the stronger a bond, the greater the energy required to break it. The energy required to break a specific covalent bond in one mole of gaseous molecules is called the bond energy or the bond dissociation energy. The bond energy for a...

Bonding in Metals

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2020

Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the “Electron Sea Model”. Electron Sea Model Most metal atoms do not possess enough valence electrons to enter into an ionic or covalent bonding. However, the valence electrons in metal atoms are loosely held due to their low electronegativity or attraction with the nucleus. The ionization energy of metal atoms (energy required to remove an electron from...

Valence Bond Theory

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2020

Overview of Valence Bond Theory Valence bond theory describes a covalent bond as the overlap of half-filled atomic orbitals (each containing a single electron) that yield a pair of electrons shared between the two bonded atoms. The orbitals on two different atoms overlap when a portion of one orbital and a portion of a second orbital occupy the same region of space. According to valence bond theory, a covalent bond results when two conditions are met: (1) an orbital on one atom overlaps an...

State Space Representation

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2024

The frequency-domain technique, commonly used in analyzing and designing feedback control systems, is effective for linear, time-invariant systems. However, it falls short when dealing with nonlinear, time-varying, and multiple-input multiple-output systems. The time-domain or state-space approach addresses these limitations by utilizing state variables to construct simultaneous, first-order differential equations, known as state equations, for an nth-order system. Consider an RLC circuit, a...

Types of Chemical Bonds

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2020

Chemical bonding theories were pioneered by American chemist Gilbert N. Lewis. He developed a model called the Lewis model to explain the type and formation of different bonds. Chemical bonding is central to chemistry; it explains how atoms or ions bond together to form molecules. It explains why some bonds are strong and others are weak, or why one carbon bonds with two oxygens and not three; why water is H2O and not H4O. Ionic Bonds Ions are atoms or molecules bearing an electrical charge.

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