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Organic Chemistry

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Alkanes and Cycloalkanes

Ethane Rotation: Staggered vs Eclipsed

Description

Ethane and propane show how rotation around a carbon-carbon single bond changes a molecule’s shape and energy. This internal rotation creates conformers, which are different arrangements of the same molecule. For ethane, the main conformations are staggered and eclipsed.

Staggered ethane is the l...

Transcript

A molecule of ethane, when viewed down the carbon-carbon bond, shows the C-H groups spaced at 60°dihedral angles. This is the staggered conformation of ethane.

The staggered form of ethane has the lowest energy. This is because the C-H bonds are furthest from each other, minimizing steric repulsion between the electrons in the bonds, and ...

Tags

Ethane ConformationsPropane ConformationsStaggered ConformationEclipsed ConformationCarbon-Carbon Bond RotationTorsional StrainDihedral AngleMolecular Orbital InteractionConformational IsomerismInternal Rotation