1.5
Partial Derivatives and Gas Laws
In functions with multiple variables, partial derivatives describe how a function changes with respect to one variable while keeping the others consta…
Consider a surface representing a function of two variables, x and y. The partial derivatives give the local slopes of the surface when one variable changes, while the other remains constant.
The partial derivative of the function z in terms of x at constant y is represented using 'curly d' notation.
For functions of two variables, the total differential sums all partial derivatives, each multiplied by the infinitesimal change in its respective variable.
Now, imagine a cylinder filled with an ideal gas. Using the ideal gas law, the change of pressure with temperature at constant volume and number of moles can be evaluated.
One approach involves rearranging the ideal gas law and then differentiating both sides by temperature, keeping all other variables constant.
This partial derivative can also be calculated from the slope of the straight line formed by plotting the pressure of an ideal gas at various temperatures, but at constant volume.
More generally, for three variables linked by an equation of state, the three partial derivatives, each taken while holding one variable constant, multiply to minus one, which is Euler’s chain rule.
View the full transcript and gain access to JoVE Core videos
Q1: What is a partial derivative and how does it differ from an ordinary derivative?
A partial derivative describes how a function changes with respect to one variable while keeping all other variables constant. For a function z = f(x, y), the partial derivative of z with respect to x at constant y is written as (∂z/∂x)y using curly d notation. Unlike ordinary derivatives that apply to single-variable functions, partial derivatives isolate the effect of one variable in multivariable systems.
Q2: How do you calculate the total differential of a multivariable function?
The total differential of a function z(x, y) is the sum of all partial derivatives, each multiplied by the infinitesimal change in its respective variable. This equation describes how infinitesimal changes in independent variables produce changes in the function. The total differential captures the combined effect of variations in all variables simultaneously.
Q3: How can you find the rate of pressure change with temperature for an ideal gas?
Using the ideal gas law pV = nRT, you can find how pressure changes with temperature at constant volume and moles. Rearrange the equation to isolate pressure, then differentiate both sides with respect to temperature while treating other variables as constants. This partial derivative (∂p/∂T)V,n equals nR/V, which matches the slope of a pressure-versus-temperature plot at constant volume.
Q4: What does Euler's chain rule tell us about interdependent state variables?
Euler's chain rule states that for three interdependent variables linked by an equation of state, the product of their partial derivatives equals minus one: (∂V/∂T)p (∂T/∂p)V (∂p/∂V)T = -1. This relation reveals that partial derivatives of p, V, and T are not independent; they satisfy a fundamental constraint. This principle is essential for analyzing how thermodynamic systems respond to changes in variables and equations of state.
Q5: Why is the partial derivative (∂V/∂T)p,n useful in gas behavior analysis?
The partial derivative (∂V/∂T)p,n represents how volume changes with temperature when pressure and moles remain constant. This quantity is critical for understanding gas expansion and contraction under fixed pressure conditions. It directly relates to the ideal gas law and helps predict how gases respond to temperature changes in real laboratory and industrial applications.
Q6: How does visualizing a multivariable function help understand partial derivatives?
Imagining a surface representing a function of two variables x and y helps visualize partial derivatives as local slopes. When one variable changes while the other remains constant, the partial derivative gives the slope of the surface in that direction. This geometric interpretation makes it easier to grasp how multivariable functions behave and why holding variables constant is essential.
Q7: What is the relationship between the ideal gas law and partial derivatives?
The ideal gas law pV = nRT serves as an equation of state linking pressure, volume, temperature, and moles. Partial derivatives of this equation reveal how each variable responds to changes in others. For example, differentiating with respect to temperature shows (∂p/∂T)V,n = nR/V, demonstrating how partial derivatives quantify the relationships embedded in the ideal gas law.