Atomic Weight

Atomic weight is the weighted average mass of an element’s naturally occurring isotopes, expressed relative to one-twelfth of the mass of a carbon-12 atom. It is calculated by multiplying each isotope’s mass by its fractional natural abundance and summing these contributions, so the value reflects both isotopic composition and the presence of multiple isotopes rather than the mass of a single atom. In chemistry, atomic weight supports mole and mass calculations, molecular formula determination, stoichiometry, and quantitative analysis. Because isotope abundances can vary in some materials, atomic weight also helps researchers interpret measurements in geochemistry, environmental science, and isotope-based studies.

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JoVE Core - Anatomy and Physiology

Atomic Weight

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2023

Protons and neutrons have approximately the same mass, about 1.67 × 10-24 grams. Scientists arbitrarily define this amount of mass as one atomic mass unit (amu) or one Dalton. Electrons are much smaller in mass than protons, weighing only 9.11 × 10-28 grams, or about 1/1800 of an atomic mass unit. As a result, they do not contribute much to an element's overall atomic mass. This means that, when considering atomic mass, it is customary to ignore the mass of any electrons and calculate the...

Atomic Mass

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2020

Atoms — and the protons, neutrons, and electrons that compose them — are extremely small. For example, a carbon atom weighs less than 2 × 10−23 g. When describing the properties of tiny objects such as atoms, we use appropriately small units of measure, such as the atomic mass unit (amu). The amu was originally defined based on hydrogen, the lightest element, then later in terms of oxygen. Since 1961, it has been defined with regard to the most abundant isotope of carbon, atoms of which are...

Atomic Orbitals

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2020

An atomic orbital represents the three-dimensional regions in an atom where an electron has the highest probability to reside. The radial distribution function indicates the total probability of finding an electron within the thin shell at a distance r from the nucleus. The atomic orbitals have distinct shapes which are determined by l, the angular momentum quantum number. The orbitals are often drawn with a boundary surface, enclosing densest regions of the cloud. The angular momentum...

Hybridization of Atomic Orbitals I

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2020

The mathematical expression known as the wave function, ψ, contains information about each orbital and the wavelike properties of electrons in an isolated atom. When atoms are bound together in a molecule, the wave functions combine to produce new mathematical descriptions that have different shapes. This process of combining the wave functions for atomic orbitals is called hybridization and is mathematically accomplished by the linear combination of atomic orbitals. The new orbitals that...

The Energies of Atomic Orbitals

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2020

In an atom, the negatively charged electrons are attracted to the positively charged nucleus. In a multielectron atom, electron-electron repulsions are also observed. The attractive and repulsive forces are dependent on the distance between the particles, as well as the sign and magnitude of the charges on the individual particles. When the charges on the particles are opposite, they attract each other. If both particles have the same charge, they repel each other. As the magnitude of the...

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