Electric Double Layer

The electric double layer is the interfacial arrangement of charge that forms when a charged surface contacts an electrolyte, governing electrical and chemical behavior at that boundary. Surface charge attracts counterions and repels co-ions, producing a compact Stern layer near the interface and a diffuse region whose ion distribution and electrostatic potential depend on electrolyte concentration, temperature, and surface charge. This structure creates interfacial capacitance and influences electron-transfer reactions, adsorption, and colloidal stability. In chemistry, electric double layers are central to electrochemical cells, corrosion studies, sensors, and supercapacitors, where controlling ion accumulation can improve performance and stability.

Electric Double Layer - Related Videos

Education

JoVE Core - Physical Chemistry

The Electrical Double Layer

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2026

In the region where two bulk phases meet, an intricate electric charge distribution arises due to charge transfer, ion adsorption, molecular orientation, and charge distortion. This complex distribution is commonly referred to as the electrical double layer.When a solid electrode interfaces with ions in an electrolyte solution, the speed of electron transfer dictates the rates of oxidation and reduction. The electrode acquires a charge through the escape of atoms into the solution as cations or...

Research

JoVE Journal - Engineering

Ohmic Contact Fabrication Using a Focused-ion Beam Technique and Electrical Characterization for Layer Semiconductor Nanostructures

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Cited by 10 •

2015

We describe the approaches for the device fabrication and electrical characterization of molybdenum diselenide (MoSe2) layer semiconductor nanostructures with different thicknesses. In addition, the fabrication of ohmic contacts for MoSe2-layer nanocrystals by the focused-ion beam deposition method using platinum (Pt) as a contact metal is described.

Electric Fields

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2023

Source: Yong P. Chen, PhD, Department of Physics & Astronomy, College of Science, Purdue University, West Lafayette, IN An electric field is generated by a charged object (referred to as the source charge) in the space around it, and represents the ability to exert electric force on another charged object (referred to as the test charge). Represented by a vector at any given point in the space, the electric field is the electrical force per unit test charge placed at that point (the force...

Education

JoVE Science Education - Physics
Free Sample

Electric Potential

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2023

Source: Yong P. Chen, PhD, Department of Physics & Astronomy, College of Science, Purdue University, West Lafayette, IN Electric potential, also known as "voltage", measures the electric potential energy per unit charge. Electric field is a scalar quantity and is fundamental to many electrical effects. Like potential energy, what is physically meaningful is the difference in the electric potential. For example, the spatial variation in the electric potential is related to the electric...

Thin-Layer Chromatography - Student Protocol

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2020

Source: Lara Al Hariri and Ahmed Basabrain at the University of Massachusetts Amherst, MA, USA Effects of Mobile Phase Composition on Compound SeparationExpand In this section of the lab, you will use TLC to compare how well pure hexane and a mixture of 60% hexane and 40% ethyl acetate can separate phenol, benzoic acid, and butyl phenyl ether by measuring the distance the compound traveled in each solvent. Before starting the lab, put on a lab coat, safety glasses, and nitrile gloves.

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