Heat Calculation

Heat calculation is the quantitative determination of thermal energy transferred during a physical or chemical change, making it central to understanding energy conservation in chemistry. In many cases, the heat absorbed or released is calculated with q = mcΔT, where q is heat, m is mass, c is specific heat capacity, and ΔT is the temperature change; calorimetry measures these changes under controlled conditions. Chemists use heat calculations to determine reaction enthalpy, compare exothermic and endothermic processes, evaluate fuel and material performance, and predict temperature changes in laboratory and industrial systems. These measurements connect molecular transformations with observable energy flow.

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JoVE Core - Chemistry
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Quantifying Heat

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2025

Thermal Energy Microscopically, thermal energy is the kinetic energy associated with the random motion of atoms and molecules. Temperature is a quantitative measure of “hot” or “cold”, which depends on the amount of thermal energy. When the atoms and molecules in an object are moving or vibrating quickly, they have a higher average kinetic energy (KE) (or higher thermal energy), and the object is perceived as “hot”, or it is described as being at a higher temperature. When the atoms and...

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JoVE Core - Chemistry

Calculating Standard Free Energy Changes

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2020

The free energy change for a reaction that occurs under the standard conditions of 1 bar pressure and at 298 K is called the standard free energy change. Since free energy is a state function, its value depends only on the conditions of the initial and final states of the system. A convenient and common approach to the calculation of free energy changes for physical and chemical reactions is by use of widely available compilations of standard state thermodynamic data. One method involves the...

Testing the Heat Transfer Efficiency of a Finned-tube Heat Exchanger

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2023

Source: Michael G. Benton and Kerry M. Dooley, Department of Chemical Engineering, Louisiana State University, Baton Rouge, LA Heat exchangers transfer heat from one fluid to another fluid. Multiple classes of heat exchangers exist to fill different needs. Some of the most common types are shell and tube exchangers and plate exchangers1. Shell and tube heat exchangers use a system of tubes through which fluid flows1. One set of tubes contains the liquid to be cooled or heated, while the second...

Calculating the Equilibrium Constant

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2020

The equilibrium constant for a reaction is calculated from the equilibrium concentrations (or pressures) of its reactants and products. If these concentrations are known, the calculation simply involves their substitution into the Kc expression. For example, gaseous nitrogen dioxide forms dinitrogen tetroxide according to this equation: When 0.10 mol NO2 is added to a 1.0-L flask at 25 °C, the concentration changes so that at equilibrium, [NO2] = 0.016 M and [N2O4] = 0.042 M. The value of the...

Heat Exchanger Analysis

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2023

Source: Alexander S Rattner and Christopher J Greer; Department of Mechanical and Nuclear Engineering, The Pennsylvania State University, University Park, PA Heat exchangers transfer thermal energy between two fluid streams, and are ubiquitous in energy systems. Common applications include car radiators (heat transfer from hot engine coolant to surrounding air), refrigerator evaporators (air inside refrigerator compartment to evaporating refrigerant), and cooling towers in power plants...

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