Ammonia Ammonium

Ammonia and ammonium are closely related nitrogen-containing chemical species that differ in charge and behavior: ammonia is the neutral molecule NH3, whereas ammonium is the positively charged ion NH4+. In water, they participate in a reversible Brønsted–Lowry acid–base equilibrium, with ammonia accepting a proton to form ammonium; the balance between the two depends strongly on pH and temperature. This relationship helps explain the properties of aqueous ammonia solutions, including their alkalinity and characteristic reactivity. In chemistry, ammonia and ammonium compounds are important in fertilizer production, buffer systems, analytical testing, and studies of nitrogen cycling in environmental and biological systems.

Ammonia Ammonium - Related Videos

Research

JoVE Journal - Bioengineering

Ammonia Synthesis at Low Pressure

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Cited by 17 •

2017

Ammonia can be synthesized at low pressure by using a conventional catalyst and an ammonia selective absorbent.

Electrochemically and Bioelectrochemically Induced Ammonium Recovery

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Cited by 31 •

2015

We demonstrate the extraction of ammonium from an ammonium-rich stream using an electrochemical and a bioelectrochemical system. The reactor setup, operation and data analysis are discussed.

Fast and Accurate Exhaled Breath Ammonia Measurement

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Cited by 16 •

2014

Ammonia is an important physiologic metabolite relevant to various disease and wellness states. It is also a difficult molecule to measure in breath, which demands particular precautions be taken to obtain accurate results. Not all factors influencing ammonia are known, but progress can be difficult without accounting for these factors.

Preparation of Hydrophobic Metal-Organic Frameworks via Plasma Enhanced Chemical Vapor Deposition of Perfluoroalkanes for the Removal of Ammonia

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Cited by 15 •

2013

Herein the procedures for plasma enhanced chemical vapor deposition of perfluoroalkanes on microporous materials such as metal-organic frameworks to enhance their stability and hydrophobicity are described. Furthermore, breakthrough testing of milligram quantities of samples is described in detail.

Education

JoVE Core - Organic Chemistry

Preparation of Amines: Alkylation of Ammonia and Amines

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2025

Alkylation is one of the methods used to prepare amines. Direct alkylation of ammonia or a primary amine with an alkyl halide gives polyalkylated amines along with a quaternary ammonium salt through successive SN2 reactions. This process of making the quaternary salt through the direct alkylation method is called exhaustive alkylation. Each alkylation step makes the nitrogen center more nucleophilic, which triggers successive alkylations until a quaternary ammonium salt is formed. Considering...

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